A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purityDeite, C. (Carl)
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A practical treatise on the manufacture of perfumery : $b comprising directions for making all kinds of perfumes, sachet powders, fumigating materials, dentrifices, cosmetics, etc., etc., with a full account of the volatile oils, balsams, resins, and other natural and artificial perfume-substances, including the manufacture of fruit ethers, and tests of their purity
Deite, C. (Carl)
Cosmetics; Perfumes; Perfumes industry
To prepare the ether bring 5½ parts of powdered potassium dichromate
together with 5 parts of water into a distilling apparatus and very
gradually add a mixture of 1 part amyl alcohol and 5 parts concentrated
sulphuric acid. The fluid becomes so strongly heated that it almost
boils. When reaction is finished, heat and distil off the rest. The
distillate consists of two layers; the lower one being an aqueous
solution of valerianic acid and the upper one a mixture of valerianic
acid and amyl valerate. To separate both, add concentrated carbonate of
soda solution until all the free acid is neutralized. The oily liquid
separating thereby is the ether. It is separated from the valerianate
of sodium, the latter evaporated to a small volume, and, after cooling,
sufficient sulphuric acid to fix the entire quantity of the soda is
added. The valerianic acid is thereby separated, and floats upon the
solution of the sodium sulphate. It is separated from the latter, and
1¼ parts of it are added to a mixture of ¾ part of amyl alcohol and 1
part sulphuric acid and heated to 212° F. After the addition of water,
the apple-ether separates and only requires washing with water and some
sodium carbonate to yield a pure product.
The separation of the valerianic acid can, however, be readily avoided.
Evaporate the neutral solution of the valerianate of soda to dryness in
the water-bath, weigh off 1 molecule, or 124 parts, and gently heat it
with a mixture of 1 molecule or 98 parts of sulphuric acid (on account
of the content of water in the commercial acid, 105 parts of it will
have to be taken) and 1 molecule or 88 parts of amyl alcohol.
The ether thus obtained is a fluid, which, in a concentrated state,
does not possess an agreeable odor, but when mixed with 10 parts of
alcohol imparts to the latter an odor resembling that of apples. It
boils at from 370° to 374° F., and at 64° F. has a specific gravity of
0.8793.
_Valerianic ethyl ether_ closely resembles the amyl ether, and, like
it, is prepared from valerianate of sodium, ordinary alcohol, and
sulphuric acid.
_Apple ether_ essentially consists of valeric amyl ether, of which 1
part is dissolved in 6 to 10 parts of strong alcohol.
_Apricot ether_ is butyric ether with some amyl alcohol.
_Cherry ether_ is acetic ether with benzoic ether.
_Pear ether_ contains acetic amyl ether.
_Pineapple ether_ is butyric ether.
_Strawberry ether_ is acetic ether with acetic amyl ether and butyric
ether.
The ethers are dissolved in various proportions in alcohol, according
to the intensity of the odor which it is desired to obtain. The
aroma of most of them is generally increased by a slight addition of
chloroform.
For the preparation of different fruit essences Kletzinsky[10] gives
the following directions. The figures indicate additions in cubic
centimeters to 1 liter of rectified alcohol of 90 per cent.:--
[10] Dingler's Polyt. Journ., 180, 77.
Public-domain text, read in full here on John Shaqi.
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