A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
_Tellurous Acid_ (TeO^{2}) is of a fine, granulous, crystalline or
white earthy mass, which is partly soluble in water. The solution has
a strong metallic taste, and an acid reaction upon litmus paper.
Heated in a tube closed at one end until it begins to glow, it fuses
to a yellow liquid which is colorless, crystalline, and opaque when
cold. Beads of it remain usually transparent like glass. Heated upon
platinum wire in the flame of oxidation, it melts, and is volatilized
as a white vapor. When heated upon charcoal in the oxidation flame, it
melts, and is reduced to the metallic state, but volatilizes and a
sublimate of white tellurous acid is formed upon the charcoal. The
edge of this deposit is usually red or dark-yellow.
Heated upon charcoal in the flame of reduction, it is rapidly reduced,
the external flame exhibiting a bluish-green color.
Borax dissolves it in the oxidation flame upon platinum wire to a
clear colorless bead which turns grey when heated upon charcoal,
through the presence of reduced metallic particles. Upon charcoal, in
the reduction flame, the bead is grey, caused by the reduced metal.
After a continued blast, tellurium is completely volatilized, and the
bead appears clear again, while a white sublimate is deposited upon
the charcoal.
With microcosmic salt, the same reactions are produced.
With carbonate of soda, tellurous acid fuses upon platinum wire to a
clear colorless bead, which is white when cold. Upon charcoal it is
reduced, and forms _tellur-sodium_, which is absorbed by the charcoal,
and metallic tellurium, which is volatilized, and deposits upon the
charcoal a white incrustation (tellurous acid).
If tellurous acid, finely powdered charcoal, and carbonate of soda are
mixed together, and the mixture be well ignited in a closed tube,
until fusion is effected, and a few drops of boiled water are brought
into the tube, they are colored purple, indicating the presence of
_tellur-sodium._
_Telluric Acid _(TeO^{3}) forms six-sided prismatic crystals. It has
not an acid, but rather a metallic taste. It changes blue litmus paper
to red; is slowly soluble in water, and rather sparingly. Exposed to
a high temperature, but not until glowing, the crystalline acid loses
its water, and acquires an orange color, but still it preserves its
crystalline form, although no longer soluble in water, and is in fact
so much changed in its properties as to present the instance of an
isomeric modification.
If telluric acid is heated gently in a closed tube, it loses water and
turns yellow. Heated still more strongly, it becomes milk-white,
oxygen is expelled, and it is converted into tellurous acid. The
presence of oxygen can be recognized by the more lively combustion
which an ignited splinter of wood undergoes when held in it. Telluric
acid produces the same reactions with the blowpipe reagents as
tellurous acid.
SEVENTH GROUP.--LEAD, BISMUTH, TIN.
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