A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
The reactions of iodine are similar to those of bromine with
concentrated sulphuric acid and binoxide of manganese, and with nitric
acid: The iodine is released and, if the quantity be not too great,
colors the liquid brown. If there be a considerable quantity of iodine
present, it is precipitated as a dark colored powder. Either of these,
when heated, gives out the violet-color of the iodine.
With starch paste free iodine combines, producing a deep blue
compound. If, however, the iodine be in very minute quantity, the
color, instead of being blue, will be light violet or rose color.
If to a solution of the sulphate of copper, to which a small portion
of sulphurous acid has been added, a liquid containing iodine and
bromine is poured in, a dirty, white precipitate of the subiodide of
copper is produced, and the bromine remains in the solution. The
latter may then be tested for the bromine by strong sulphuric acid.
(11.) _Fluorine_ (Fl).--This element exists combined with sodium,
calcium, lithium, aluminium, magnesium, yttrium, and cerium. Fluorine
also exists in the enamel of the teeth, and in the bones of some
animals. This element has a strong affinity for hydrogen, and,
therefore, we find it frequently in the form of hydrofluoric acid.
Brazil-wood paper is the most delicate test for hydrofluoric acid,
which it tinges of a light yellow color. Phosphoric acid likewise
colors Brazil paper yellow, but as this acid is not volatile at a heat
sufficient to examine hydrofluoric acid, there can be no mistake. If
the substance is supposed to contain this acid, it should be placed on
a slip of glass, and moistened with hydrochloric acid, when the test
paper may be applied, and the characteristic yellow color will
indicate the presence of the fluorine.
As hydrofluoric acid acts upon glass, this property may be used for
its detection. The substance may be put into a glass tube, and
sulphuric acid poured upon it in sufficient quantity to moisten it; a
slight heat applied to the tube will develop the acid, which will act
upon the glass of the tube. If the acid is retained in the mineral by
a feeble affinity, and water be present, a piece of it may be put in
the tube and heated, when the acid gas will be eliminated. The test
paper will indicate its presence, even before it has time to act upon
the glass. If the temperature be too high, fluosilicic acid is
generated, and will form a silicious incrustation upon the cool
portion of the tube.
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