A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
When in very large proportion dissolves to a clear glass, having
a yellow tinge, while hot, which disappears on cooling, and when
perfectly saturated, becomes milk-white.
in the reducing flame.
On charcoal the oxide is slowly and imperfectly reduced. The
reduced metal forms the characteristic incrustation on the
charcoal, but the is thin and does not exhibit its color clearly
until quite cold. The addition of tin hastens the reaction.
* * * * *
10. Oxide of Lead, PbO.
Behavior with Borax on Platinum wire
in the oxidizing flame.
Dissolves readily to a clear yellow glass, which loses its color
upon cooling, and when containing much oxide can be rendered
dull under an intermittent flame. With a still larger addition
of oxide it becomes opaline yellow on cooling.
in the reducing flame.
The plumbiferous glass spreads out on charcoal, becomes turbid,
bubbles up, until the whole of the oxide is reduced, when it
again becomes clear. It is, however, difficult to bring the lead
together into a bead.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
As with borax, but a larger addition of oxide, required to
produce a yellow color in the warm bead.
in the reducing flame.
On charcoal the plumbiferous glass becomes grey and dull. With
an over dose of oxide a part is volatilized and forms an
incrustation on the charcoal beyond the bead. The addition of
tin does not render the glass opaque, but somewhat more dull and
grey than in its absence.
* * * * *
11. Oxide of Tin, SnO^{2}.
Behavior with Borax on Platinum wire
in the oxidizing flame.
In small quantity dissolves slowly into a clear colorless glass,
which, when cold, remains clear, and cannot be rendered opaque
with an intermittent flame. If a saturated bead, which has been
allowed to cool, be reheated to incipient redness, it loses its
rounded form and exhibits imperfect crystallization.
in the reducing flame.
A glass containing but little oxide undergoes no change. If much
of the latter be present, a part may be reduced upon charcoal.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
In small quantity dissolves very slowly to a colorless glass,
which remains clear on cooling.
in the reducing flame.
The glass undergoes no change, either on charcoal or platinum wire.
* * * * *
12. Oxide of Bismuth, BiO^{3}.
Behavior with Borax on Platinum wire
in the oxidizing flame.
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