A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
On charcoal, the saturated glass becomes at first dull, but as
soon as the reduced antimony is volatilized, it again becomes
clear. With tin, the glass is at first rendered grey by the
reduced antimony, but by continued blowing is restored to
clearness. Even when the glass contains but little oxide, tin
produces this reaction.
* * * * *
29. Tungstic Acid, WO^{3}.
Behavior with Borax on Platinum wire
in the oxidizing flame.
Dissolves readily to a clear colorless glass. In large
proportion it renders the borax yellow, while warm, and with a
still greater addition the bead may be made opaque with an
intermittent flame. If more be then added, this reaction takes
place spontaneously.
in the reducing flame.
When the oxide is present in small quantity, the glass undergoes
no change. With a larger proportion, the glass is deep yellow
while warm, and yellowish-brown when cold. This reaction takes
place upon charcoal, with a small quantity of the acid. Tin
produces a dark coloration, when the acid is not present in too
great a quantity.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
Dissolves to a clear glass, which, when saturated, is yellow in
the hot state.
in the reducing flame.
The glass is of a pure blue. If the tungstic acid contain iron,
the glass becomes blood-red on cooling, similar to titanic acid.
In this case, tin restores the blue color, or, if iron be in
considerable quantity, renders it green.
* * * * *
30. Molydbic Acid, MO^{3}.
Behavior with Borax on Platinum wire
in the oxidizing flame.
Dissolves readily and in large quantity. When but little is
dissolved, the glass is yellow while hot and colorless when
cold. When in larger quantity yellow while warm and opaline when
cold, and a further addition of acid renders it yellow when
warm, the color, on cooling, changing first to a pale enamel
blue, and then to an enamel white.
in the reducing flame.
The glass, which has been treated in the oxidizing flame,
becomes, when the acid is not present in too large a quantity,
brown, and when in large quantity, perfectly opaque. In a
strong flame, oxide of molybdenum is formed which is visible in
the yellow glass in the form of black flakes. If the glass
appear opaque, it should be flattened with the forceps.
Behavior with Mic. Salt on Platinum wire
in the oxidizing flame.
Dissolves to a clear glass, which, when sufficient acid is
present, is of a yellowish-green color when warm, and becomes
nearly colorless on cooling. On charcoal, the glass becomes
dark, and when cool has a beautiful green color.
in the reducing flame.
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