A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
The carbonate of soda is pulverized and then kneaded to a paste with
water; the substance to be examined, in fine powder, is also mixed
with it. A small portion of this paste is placed on the charcoal, and
gradually heated until the moisture is expelled, when the heat is
brought to the fusion of the bead, or as high as it can be raised.
Several phenomena will take place, which must be closely observed.
Notice whether the substance fuses with the bead, and if so, whether
there is intumescence or not. Or, whether the substance undergoes
reduction; or, whether neither of these reactions takes place, and, on
the contrary, the soda sinks into the charcoal, leaving the substance
intact upon its surface. If intumescence takes place, the presence of
either tartaric acid, molybdic acid, silicic, or tungstic acid, is
indicated. The silicic acid will fuse into a bead, which becomes clear
when it is cold. Titanic acid will fuse into the bead, but may be
easily distinguished from the silicic acid by the bead remaining
opaque when cold.
Strontia and baryta will flow into the charcoal, but lime will not.
The molybdic and tungstic acids combine with the soda, forming the
respective salts. These salts are absorbed by the charcoal. If too
great a quantity of soda is used, the bead will be quite likely to
become opaque upon cooling, while, if too small a quantity of soda is
used, a portion of the substance will remain undissolved. These can be
equally avoided by either the addition of soda, or the substance
experimented upon, as may be required.
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