A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(_B._) _Sesquioxide of Cerium_ (Ce^{2}O^{3}).--This oxide, in the pure
state, is a red powder. When heated with hydrochloric acid, it
produces chlorine gas, and is dissolved to a salt of the protoxide. It
is not affected by either the flame of oxidation or of reduction; when
fused with borax or microcosmic salt, it acts like the protoxide. It
does not fuse with soda upon charcoal. In the reduction flame it is
reduced to the protoxide, which remains of a light grey color, while
the soda is absorbed by the charcoal.
(_b._) _Lanthanium_ (La.)--This metal is invariably associated with
cerium. It presents, in its metallic state, a dark grey powder, which
by compression acquires the metallic lustre.
The _oxide of lanthanium_ (LaO) is white, and its salts are colorless.
Heated upon charcoal, it does not change either in the oxidation flame
or that of reduction. With borax, in the flame of oxidation or
reduction, it gives a clear colorless bead. This bead, if saturated,
and when hot, presents a yellow appearance, but is clouded or
enamelled when cold. With microcosmic salt the same appearance is
indicated. It does not fuse with carbonate of soda, but the soda is
absorbed by the charcoal, while the oxide remains of a grey color.
(_c._) _Didymium_ (D).--This metal occurs only in combination with the
preceding ones, and it is therefore, like them, a rare one.
_Oxide of Didymium_ (DO).--This oxide is of a brown color, while its
salts present a reddish-violet or amethyst color. The oxide is
infusible in the oxidation flame, and in that of reduction it loses
its brown color and changes to grey. With borax in the oxidation
flame, it fuses to a clear dark red or violet bead, which retains its
clearness when highly saturated with the oxide, or if heated with a
fluctuating flame.
The reactions with microcosmic salt are the same as with borax.
It does not melt with carbonate of soda upon charcoal, but the oxide
remains with a grey color, while the soda is absorbed by the charcoal.
(_d._) _Columbium,_ (_Tantalum_--Ta).--This rare metal occurs quite
sparingly in the minerals _tantalite_, _yttrotantalite_, etc., as
columbic acid. In the metallic state, it presents the appearance of a
black powder, which, when compressed, exhibits the metallic lustre.
When heated in the air it is oxidized into columbic acid, and is only
soluble in hydrofluoric acid, yielding hydrogen. It is oxidized by
fusion with carbonate of soda or potash.
_Columbic Acid_ (Ta^{2}O^{3}) is a white powder, and is infusible.
When heated in the flame of oxidation or reduction, it appears of a
light yellow while hot, but becomes colorless when cold. With borax,
in the flames of oxidation and reduction, it fuses to a clear bead,
which appears by a certain degree of saturation, of a yellow color so
long as it continues hot, but becomes colorless when cold. If
overcharged, or heated with an intermittent flame, it presents an
enamel white when cool.
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