A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(_f._) _Pelopic Acid_ (PeO^{3}).--This acid is white, and appears
yellow when heated, but resumes its white color when cold. Borax
dissolves it in the oxidation flame to a clear colorless bead, which
appears, when overcharged and heated intermittingly, enamel-white when
cold. This is likewise the case in the flame of reduction, but when
overcharged the color is light grey, when the bead is cooled.
Microcosmic salt dissolves it in the flame of oxidation, to a clear
yellow bead, which loses its color when cold. In the reduction flame,
when the bead is highly saturated, a violet-brown color is produced.
In presence of the oxides of iron, the reactions are like those of
niobic acid. With carbonate of soda, the reactions are similar to
those of niobic acid. By heating with nitrate of cobalt, it yields a
light grey infusible mass.
(_g._) _Titanium_ (Ti).--This metal occurs occasionally in the slags
of iron works, in the metallic state, as small cubical crystals of a
red color. It is a very hard metal, and very infusible. Titanic acid
occurs in nature crystallized in _anatase_, _arkansite_, _brookite_,
and _rutile_. Titanium is harder than agate, entirely infusible, and
loses only a little of its lustre, which can be regained by fusion
with borax. It does not melt with carbonate of soda, borax, or
microcosmic salt, and is insoluble in every acid except the
hydrofluoric. By ignition with saltpetre it is converted into titanic
acid, which combines with the potassium, forming the titanate of
potassium.
_Titanic Acid_ (TiO^{2}) is white, insoluble, and, when heated, it
appears yellow while hot, but resumes upon cooling its white color.
Borax dissolves it in the oxidation flame to a clear yellow bead,
which when cool is colorless. When overcharged, or heated with the
intermitting flame, it is enamel-white after being cooled. In the
reduction flame, the bead appears yellow, if the acid exists in small
quantity, but if more be added, then it is of an orange, or dark
yellow, or even brown. The saturated bead, when heated intermittingly,
appears when cold of an enamelled blue. By addition of the acid, and
by heating the bead on charcoal in the reduction flame, it becomes
dark yellow while hot, but dark blue, or black and opaque when cold.
This bead appears, when heated intermittingly, of a light blue, and
when cold, enamelled.
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