A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Although animal substances, by putrefaction, furnish azote,
and nascent azote unites with facility with the oxygen of the
atmosphere, by which nitric acid is generated--(hence the
spontaneous decomposition of nitre composts)--yet Vauquelin is of
opinion, that the presence of calcareous or alkaline substances
is indispensable, and that the production of carbonate of ammonia
from the animal matter, is another compound, which results from
the same decomposition. Ammonia is produced by the union of azote
and hydrogen, and carbonic acid by that of carbon and oxygen. He
considers then, that the presence of lime, magnesia, potash, &c.
_determines_ the union of the azote with oxygen, and of course, the
formation of nitric acid; and as this acid unites with one or other
of these substances, according to circumstances, we have either
nitrate of lime, or of magnesia, or nitrate of potassa. The idea
that water is decomposed in the change which animal and vegetable
substances undergo, in the process of nitrification, is contrary
to observation; for the presence of air in dry situations, is
indispensable to the process.
If a compost, made up of animal, vegetable, and calcareous
substances, and put in small beds or heaps, and covered with a shed
open at both sides, be frequently turned to admit new surfaces to the
air, and occasionally moistened with urine, &c.--nitric acid will be
generated as the putrefaction goes on. When this process is suffered
to proceed until the decomposition is complete, and the beds then
lixiviated, the quantity of nitre will be considerable. In all cases,
we are to observe, that, as various earthy nitrates are produced,
and mostly nitrate of lime, potash, or wood-ashes which contain this
alkali, are to be used.
It was long since shown by Glauber, that a vault plastered over with
a mixture of lime, wood-ashes, and cows' dung, soon becomes covered
with efflorescent nitre; and that, after some months, the materials
yield, on lixiviation, a considerable proportion of this salt. M. de
Roder, speaking of nitrous walls, observes, that the efflorescence of
nitre on them is in consequence of the stone, lime, and sand employed
in the building.
Public-domain text, read in full here on John Shaqi.
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