A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
1st. By the eprouvette of Darcy, consisting of a cannon, which, being
suspended to the extremity of a bar of iron, described by its recoil
an arc, of which the degrees can be measured.
_Recoil._
2 drachms muriatic powder, 15 deg. 2/20
2 ---- do do moistened, 14 -- 1/20
2 ---- common powder, 10 -- 7/20
2 drachms common powder, 10 -- 1/20
3 ---- muriatic powder, 20 -- 9/20
3 ---- common powder, 16 -- 6/20
From these results, it appears, that, by the eprouvette of Darcy, the
muriated powder, or that prepared with chlorate of potassa, gave a
superiority of force of about one-fourth.
2nd. By the eprouvette of Regnier, which is repelled by the
explosion, to a distance greater or less, measured by the degrees of
the arc which it describes:
Muriated powder, 42
Idem, 51¾
Idem, moistened, 52
Common powder, superfine, 23
Idem, 22½
From which it results, that by the eprouvette of Regnier, the force
of the powder of the oxymuriate is double that of the nitrate, or
common powder.
M. Ruggieri is of opinion, that chlorate, or hyperoxymuriate of
potassa may be employed with advantage in the composition of rockets,
but we have not heard that it has been used. It is more powerful in
its effects, and probably for this reason he recommended it. This
salt, mixed with other substances, will produce the _green fire_ of
the palm-tree, in imitation of the Russian fire.
Chloric acid may be obtained in a separate state, by boiling the
compound solution formed by passing chlorine gas through a solution
of barytic earth, with phosphate of silver, which separates the
muriatic acid. By evaporation, the chlorate of barytes will
crystallize in fine rhomboidal prisms. When these crystals are
dissolved in water, and diluted sulphuric acid added by degrees,
an acid liquid will be obtained, which, if the sulphuric acid be
added cautiously, will be found entirely free from the latter acid
and barytes, and not affected by nitrate of silver. This is the
chloric acid dissolved in water. Chloric acid unites with sundry
bases. Combined with ammonia, it forms a fulminating salt, formerly
described by M. Chenevix. This salt is formed, by mixing together
carbonate of ammonia, and chlorate of lime. The carbonate of lime
is then separated by the filter, and the clear liquid, holding the
chlorate of ammonia in solution, is evaporated. Chlorate of ammonia
is very soluble in water and alcohol, and decomposed by a moderate
heat.
Chlorates, as the chlorate of potassa, are formed more readily
in the manner already stated: _viz._ by saturating the base with
chlorine, but in this case two salts are produced, the chlorate and
hydrochlorate. Chloric acid has also been obtained in a separate
state, from chlorate of potassa, by a process recommended by Mr.
Wheeler.
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