A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Before we give the gaseous products, according to these gentlemen,
it will be necessary to observe, that the quantity of nitric acid
in nitrate of potassa, is 48.62 in the hundred, and according to
Gay-Lussac, nitric acid is composed in volume of 250 oxygen and 100
azote, or in weight of 69.488 oxygen, and 30.512 azote.
Using the French _gramme_ in the present instance, it appears that
75 grammes of nitrate of potassa, the proportion of this salt which
enters into 100 grammes of gunpowder for war, contains 36.47 grammes
of nitric acid; and that this quantity of acid is formed of 25.34
grammes of oxygen, and 11.13 grammes of azote. That quantity of
oxygen (25.34) is disengaged from its combination with azote in the
nitric acid, at the instant of the inflammation of the powder by the
charcoal, forming carbonic acid; the constituents of which, according
to the proportions established by Gay-Lussac and others, must be in
the ratio of 27.376 of carbon and 72.624 of oxygen. If 25.34 grammes
of oxygen exist in 75 grammes of nitrate of potassa, the proportion
usually admitted, then it will require 9.55 grammes of carbon to
saturate it, so as to produce carbonic acid. It is necessary to
consider, that this is independent of any foreign earthy or saline
matter or moisture which may exist.
With respect to the presence of hydrogen in charcoal, the
observations of Dr. Priestley, Cruikshanks, Kirwan, Berthollet,
Gay-Lussac, Thenard, Vauquelin, Lowitz and some others, are
conclusive on that head. Lavoisier made the quantity of hydrogen in
charcoal upon an average, to be 0.125 of its weight. See _Memoirs de
la Société d'Arcueil_, tome ii, p. 343, and the _Statique Chimique_,
tome ii, pages 44 and 45, and also _charcoal_ in a preceding section.
It is said, that by employing more charcoal than is necessary to
decompose the nitric acid of the nitre, the excess passes off, not
as carbonic acid, but carbonic oxide, or gaseous oxide of carbon,
which is necessarily inflamed, and finally forms carbonic acid, as
one of the products with the carbonic acid originally formed. But the
carbonic oxide, to be changed into carbonic acid, requires in fact
the oxygen of the atmosphere.
If 34.89 grammes of carbonic acid result from the combustion of
9.55 grammes of carbon, it must unite with a quantity of oxygen,
as before expressed, and according to the temperature, be more or
less expanded. The 11.13 grammes of azote thus disengaged from its
combination with oxygen, in the nitric acid, remains, of course, in
the gaseous state, and is also expanded by caloric. The quantity of
the latter is stated by Lavoisier, to be 430 degrees, using a scale
of 80 parts; and according to more recent experiments, it is fixed
at 600 degrees of the centigrade thermometer. The experiments of
Gay-Lussac are more recent, in which he has given the dilatation
of the gases, and the quantity of free caloric evolved, which
corresponds with the last data. We have not room to insert his
remarks.
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