A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
The sulphur is not (properly speaking) a necessary ingredient
in gunpowder, since nitre and charcoal alone, well mixed, will
explode; but the use of the sulphur seems to be to diffuse the
fire instantaneously through the whole mass of powder. But, if the
following experiments are correct, it should seem that the advantage
gained by using sulphur in increasing the force of explosion only
applies to small charges; but in quantities of a few ounces, the
explosive, or at least the _projecting_ force of powder without
sulphur, is full as great as with sulphur.
The following are a few out of many trials made at the Royal
Manufactory at Essonne, near Paris, in the year 1756, to determine
the best proportions of all the ingredients. Of powder made with
nitre and charcoal alone, 16 of nitre and 4 of charcoal was the
strongest, and gave a power of 9 in the eprouvette. With all three
ingredients, 16 of nitre, 4 of charcoal, and 1 of sulphur, raised the
eprouvette to 15, and both a less and a greater quantity of sulphur
produced a smaller effect. Then diminishing the charcoal, a powder
of 16 of nitre, 3 of charcoal, and 1 of sulphur gave a power of 17
in the eprouvette, which was the highest produced by any mixture.
This last was also tried in the mortar-eprouvette against the common
proof powder, and was found to maintain a small superiority. The
powder made without sulphur in the proportions above indicated was
also tried in the mortar-eprouvette, and with the following singular
result: when the charge was only two ounces it projected a sixty
pound copper ball 213 feet, and the strongest powder with sulphur
projected it 249 feet; but in a charge of three ounces, the former
projected the ball 475 feet and the latter only 472 feet; and on the
other hand the great inferiority of force in the smaller eprouvette
of the powder without sulphur has been just noticed.
It is a fact, known from time immemorial, that by the combustion of
bodies caloric is generated, or chemically speaking, is given out in
a free state; but the cause was not known until the anti-phlogistic
theory of chemistry was established, which abolished as untenable
the old doctrine of phlogiston; The quantity of caloric, which
passes from a latent to a free state in combustion, as combustion
is nothing more than the phenomena occasioned by this transition,
is variable; and depends therefore on the substances burnt, and the
nature of what is denominated the supporter of combustion.
Public-domain text, read in full here on John Shaqi.
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