A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
The process for preparing Howard's fulminating mercury is the
following, dissolve one hundred grains of mercury in an ounce and a
half (by measure) of common nitric acid, assisting the solution by
heat. When cold, pour the solution upon two ounces (by measure) of
strong alcohol, and apply a moderate heat, until the mixture begins
to effervesce. A white fume then begins to undulate on the surface of
the liquor, and a white powder precipitates, which is the fulminating
mercury. This powder is to be immediately washed with cold water,
and dried at a heat, not much exceeding that of boiling water. One
hundred grains of mercury, will give, on an average, one hundred and
twenty-five grains of the powder.
The products of its combustion are carbonic acid gas, azotic gas,
water, and mercury. Besides by percussion, it is inflammable when
brought in contact with sulphuric acid. It is supposed, that
fulminating mercury sometimes contains ammonia, and that the products
of combustion, according to the mode of preparation, are therefore
different. The reader may consult some interesting observations on
this powder in the _Journal de l'Ecole Polytechnique_.
M. Bayen, an apothecary, in 1779, (_Journal de Physique_), announced
a process for preparing fulminating mercury. His process, however,
is different from that described. A solution of mercury is made in
nitric acid, and precipitated by caustic alkali. The precipitate
(oxide of mercury) is then caught on a filter, washed, and dried.
Thirty grains of this powder, mixed with four or five grains of
sulphur, and struck with a heavy hammer, or heated on an iron, will
explode with violence. The oxide of mercury, obtained from its
solution by lime-water, has the same effect, when treated in the same
manner. Another process recommended is, to precipitate a solution of
the perchloride of mercury (corrosive sublimate) by lime-water, and
treat the precipitate with sulphur, as above described.
_Sect. XXVI. Of Fulminating Silver._
This compound, which is more powerful than fulminating mercury, is
prepared also with alcohol. Descostils (_Annales de Chimie_, LXII. p.
198,) Cruikshank, and Brugnatelli, have all written upon it.
Fulminating silver explodes without much heat. By the slightest
friction it is inflamed, and detonation follows. Hence it is used in
the form of toys, in fulminating balls, bombs, crackers, &c. which
explode by falling on the ground. Torpedoes, pulling crackers, &c.
are formed of this powder. The fulminating balls are made of glass,
and contain a grain or two of fulminating silver, mixed with sand.
The same mixture, put on the ends of two strips of paper, and the
ends pasted, forms the pulling crackers; for the moment they are
pulled asunder, the friction produced sets the fulminating silver on
fire, and causes a detonation.
Public-domain text, read in full here on John Shaqi.
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