A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
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A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Arsenic combines readily with sulphur. When they are mixed together,
and put into a crucible and fused, the product will be a red vitreous
mass. This red sulphuret may also be formed, by melting sulphur with
arsenious, or arsenic acid. Sulphurous acid gas will be evolved,
evidently showing that a portion of the sulphur unites with the
oxygen of acid employed.
When arsenious acid, known in commerce by the name of white arsenic,
and called by some oxide of arsenic, is dissolved in muriatic acid,
and a solution of sulphuretted hydrogen in water is added, a yellow
precipitate will be obtained which is orpiment. The hydrogen, in
this case, unites with the oxygen of the arsenious acid, by which the
metal is reduced, and the sulphur then combines with it. A mixture of
sulphur and arsenic, exposed to a heat not sufficient to melt them,
will sublime into a yellow sulphuret.
Both the yellow and red sulphurets are employed in fire-works. They
are not, however, required, except in particular cases. In the
composition of Bengal lights, given in the Bombardier or Pocket
Gunner, by R. W. Adye, orpiment is used. According to the same
author, it is also used in Chinese white lights. Both the yellow and
red sulphuret of arsenic will detonate with chlorate of potassa.
_Sect. XXXVI. Of Antimony._
The antimony, which enters into the composition of many fire-works,
is not to be understood to be the metallic, or regulus of, antimony,
unless so expressed; but the crude antimony of the shops. Crude
antimony is a combination of antimony and sulphur, and is usually
met with in fine powder. That both antimony and its sulphuret have
a powerful effect in modifying the flame of gunpowder, and all
compositions, in which nitre and inflammable substances form a part,
is evident from the many cases, in which it is employed, and from the
effects that thereby result.
The different substances in any inflammable compound, intended
to produce particular colours, should be so mixed, as that, from
a knowledge of the proportions which produce such colours, the
_effect_ may be retained, even when it is mixed with other bodies.
For this reason, the artist should know the different effect of each
ingredient. Some may show themselves in the flame, some in sparks,
some in stars, others in fire-rain, and the like, as the case may
be. Antimony, for instance, produces a reddish flame, if it be
in a proper proportion, and not altered by the presence of other
substances. Hence, when antimony is mixed with nitre, the flame will
be more or less a _whitish-green_.
Public-domain text, read in full here on John Shaqi.
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