A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
The modifications, to which particular bodies are subject, as to
their respective effects, depend very greatly on the presence of
other bodies, and frequently on the chemical action, which ensues
throughout; so that, as we had occasion to observe, the _effect_
which one body would produce on the flame, maybe completely changed,
modified, or varied by the presence of a second, third, or fourth
substance. The art, therefore, of uniting various bodies, in kind,
as well as in proportion, so as to produce a given effect, can be
acquired only by a series of experiments. Zinc, as a metal, when
finely divided, produces a peculiar effect; when mixed with other
metals, and with certain salts, as sal ammoniac, another; and, when
combined with some acids, as the carbonic in lapis calaminaris, a
third effect; and these effects may be governed, as it appears, by
the presence or absence of certain bodies. This fact will appear
more striking, when we consider the various mixtures, and their
respective properties. For the uses of zinc, see that article.
_Sec. XLII. Of Zinc._
Zinc, commonly called spelter, is a metal, obtained from blende,
or sulphuret of zinc, and calamine, or carbonate of zinc. The ore
is first roasted, and then mixed with some carbonaceous flux, and
submitted to the action of heat in close vessels. The metal is
volatilized, and passes over, and is usually caught in water. It is
then fused, and cast in moulds.
Zinc possesses many remarkable properties, some of which are the
following. It is of a brilliant white colour, with a shade of blue,
and is composed of a number of thin plates, adhering together. Its
specific gravity is more than six times that of water. It is brittle,
but, when heated to 212 degrees, may be hammered out, or made into
sheets. At 400° it becomes very brittle. Its tenacity is so feeble,
that a wire of 1/10th of an inch in diameter, will support a weight
of only 26 pounds. At 680° it melts, and above that temperature,
evaporates. It soon oxidizes, and its lustre is therefore tarnished.
At common temperatures, it soon decomposes water; and, when the
vapour of water is passed over it at a high temperature, the
decomposition is very rapid, the oxygen of the water being absorbed.
Zinc is soon oxidized when melted and exposed to the air, forming a
gray oxide.
At a red heat, zinc inflames, and the product of combustion is the
white oxide of zinc, or flowers. The oxide of zinc is reduced by
mixing it with charcoal, and exposing the mixture to a strong heat in
close vessels.
Zinc will burn in chlorine gas, and forms a chloride of zinc. If the
perchloride of mercury and zinc-filings be heated together, the same
compound will result. This chloride melts at 212°, and rises, in the
gaseous form, at a heat much below ignition. It was formerly called
the _butter of zinc_, and muriate of zinc. With iodine, zinc forms a
compound, called iodide of zinc.
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