A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Zinc readily unites with copper; and the usual manner of forming
brass by brass-founders, is to make a direct union between the two
metals. The process, however, generally consists in mixing together
granulated copper, calamine, or carbonated oxide of zinc, and
charcoal in powder, and melting them in a crucible. The charcoal
reduces the zinc, which then unites with the copper. The heat is kept
up for five or six hours, and towards the last of the process, is
raised. Zinc, in small proportion, renders copper pale, and in the
proportion of one-twelfth, inclines its colour to yellow. The yellow
colour increases in intensity with the zinc, until the weight of this
metal in the alloy equals that of the copper. An increase of zinc,
afterwards makes the alloy white. English brass contains one-third
of its weight of zinc. In Germany and Sweden, the proportion of zinc
varies from one-fifth to one-fourth of the copper. Twenty to forty
parts of zinc, with eighty to sixty parts of copper form the _cuivre
jaune_, laiton, or yellow copper of the French.
Dutch metal, or Dutch gold, is a fine kind of brass, and comes in
leaf, which is about five times as thick as gold leaf. This brass is
made by the cementation of copper plates with calamine, and hammered
out into leaves.
According to Thenard (_Traité de Chimie_, tome i, p. 478), the
French use 50 parts of calamine, mixed intimately with 20 parts of
charcoal, and stratified in a crucible with 30 parts of laminated, or
granulated copper. British brass consists of two parts of copper, and
1-1/8 parts of zinc, by weight.
The filings of brass are much employed in fire-works. They
communicate to stars, rains, &c. a flame between a blue and green. In
some, the filings of copper alone are used. A beautiful green fire,
for instance, is produced by 16 ounces of gunpowder, and 3-1/4 ounces
of copper-filings. Verdigris is also employed for the same purpose;
but the effect is not so striking, as in that preparation, the copper
is already oxidized. The effect of copper in fire-works, it is to be
recollected, depends, like that of other metals, on its combustion,
and consequent oxidizement. The product of the combustion of brass,
is oxide of copper, and oxide of zinc.
_Sec. XLIV. Of Bronze._
The union of copper with tin, in various proportions, forms
gun-metal, bell-metal, the mirrors of telescopes, and bronze.
The ductility of the copper is diminished by the tin; but its
hardness, and tenacity, as well as its fusibility and sonorousness
are increased.
To form a complete union of the two metals, they should be continued
in fusion for some time, and constantly stirred. The tin is apt to
rise to the surface, unless this precaution is used.
Bronze is usually composed of 100 parts of copper, and 8 to 12 parts
of tin. It is yellow, brittle, heavier than copper, and has more
tenacity.
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