A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
As the brilliancy of the sparks, produced by the iron and steel dust,
is a desideratum in the formation of some fire-works, and as this
brilliancy depends upon the nature and quality of the metal, it may
not be improper to offer some remarks on these subjects.
That iron, when finely divided is capable of producing sparks of
fire, is a well known fact; and we see it daily in the operations
of the smith, when ignited iron is hammered on the anvil. The
scintillation produced by the steel, when struck with a flint, is of
the same character. In the latter case, the metal is actually fused,
and, when caught on a paper, and examined with a microscope, will
appear globular, and partly oxidized. Hence it is, that gunpowder is
inflamed by this spark, which is nothing more than highly ignited,
and inflamed iron, possessing a temperature more than sufficient to
inflame gunpowder.
The effect, therefore, that results from the inflammation of
fire-works, in which iron or steel forms a constituent part, is
nothing more than a vivid combustion of the metal; and during that
process it becomes oxidized, as it does not form an acid with oxygen,
like arsenic, antimony, and some other metals.
The combustion of iron or steel may be shown by a very brilliant
experiment, that of burning it in oxygen gas. A steel wire,
harpsichord wire for instance, formed into a spiral, with a small
piece of wood dipped in sulphur, stuck on its end and then set on
fire, upon being immediately introduced into a bottle, containing
pure oxygen gas, will burn with great brilliancy, emitting a number
of sparks or scintillations, which fall like rain. In making the
experiment, some sand should be put into the bottle to prevent the
sparks from breaking it. This experiment illustrates the rapid
combustion of iron, or steel. For the oxygen gas supports the
combustion; and while the oxygen is actually taken up by the metal,
which becomes oxidized, and therefore increased in weight, in the
same manner as it does when inflamed in fire-works, the caloric, the
other constituent of oxygen gas, is given out in a free state, and,
with the light at the same time evolved, produces the phenomena of
combustion.
Public-domain text, read in full here on John Shaqi.
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