A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
Gun barrels are browned by a process of oxidizement. There are
several processes recommended. One of which is, to rub the barrel
over with diluted nitric or muriatic acid, and then, to lay it by
for a week or two, until a complete coat of rust is formed. A brush,
made of iron wire, is then applied; afterwards, oil and wax, and
the barrel is finished by rubbing it with a cloth. The gunsmiths in
Philadelphia use a mixed solution of sulphate of copper, tincture
of the muriate of iron, and sweet spirit of nitre. This they apply
by means of a cloth. The object is to form a rust, and to render
it permanent on the barrel by hard friction along with wax. When
sulphate of copper is employed, metallic copper is precipitated
on the barrel. A coat of rust, put on in this manner, prevents
effectually the oxidizement of the iron; and in point of utility, and
the saving of labour in polishing and keeping muskets in order, the
browning of barrels is certainly advantageous in the land service.
At sea, in particular, where iron is more readily oxidized, this
plan ought always to be adopted. With regard to the use of dragon's
blood, it is entirely too temporary in its effect to be depended on.
I was informed by an intelligent gunsmith, who followed the practice
of browning barrels in Europe, that he has known the _browning_ to
remain very perfect for years, and that the best mode of insuring its
durability is to use the _steel brush_, which _carries in_, as he
expressed it, the rust.
The oxides, which are formed by the union of oxygen with iron, are
two; namely, the black and the red; the first being the protoxide,
and the last the peroxide. The black oxide, which is formed by
the combustion of iron, and by other processes, contains 56 iron
+ 16 oxygen. The common rust of iron is the peroxide of this
metal, combined with carbonic acid. It may be formed by exposing
the protosulphate of iron, or green vitriol, in solution, to the
atmosphere, and then adding an alkali. This oxide contains more
oxygen than the preceding; it consisting of 56 iron + 24 oxygen.
The tempering of cutting instruments, an operation which requires
great delicacy and exactness, after that of hardening, is intended
to obtain a fine and durable edge; and as this subject may be
interesting in a military point of view, we deem the following
remarks of use.
Public-domain text, read in full here on John Shaqi.
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