A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.Cutbush, James
History
A system of pyrotechny : $b Comprehending the theory and practice, with the application of chemistry; designed for exhibition and for war.
Cutbush, James
Fireworks; Military fireworks
When three parts of nitre, two parts of potash, and one of sulphur,
all previously well dried, are mixed together, the compound is called
_pulvis fulminans_, or, _fulminating powder_. A small portion of this
powder, or as much as will lay on a shilling-piece, put on a shovel,
and exposed to heat, will first melt, become liver-coloured, and
then explode with great noise. The theory of this explosion is, that
a part of the sulphur, and the potassa unite, and form a sulphuret;
the sulphuret then decomposes water, and produces sulphuretted
hydrogen gas, which appears to be decomposed by the nitric acid; and
there results sulphurous acid gas, water, and, as Thenard observes,
protoxide of azote, azotic gas, and sulphate of potassa. The loudness
of the report depends on the combustion of the whole powder at the
same instant, which is secured by the previous fusion it undergoes.
Gunpowder, on the contrary, burns in succession, although apparently
instantaneous. In using common potash, there is also, as the alkali
contains it, carbonic acid, given out in the state of gas. In fact
carbonic acid appears to assist the explosive effect of this powder,
for when it is prepared with potash, containing little carbonic acid,
its detonating power is considerably less.
Nitre likewise enters into the composition of another fulminating
powder, invented by Dr. Higgins. _Higgins's fulminating powder_ is
composed of three and a half parts of nitre, two parts of crude
antimony, and one part of sulphur. This is used in the same manner as
the former.
Nitre enters into the composition of gunpowder, which we shall
notice under a separate head. The proportions of nitre, sulphur,
and charcoal, for the formation of gunpowder, which are considered
the best, are, 75 parts of nitre, 12-1/2 of charcoal, and 12-1/2 of
sulphur.
The new powder of MM. Gengembrie and Bottée, which inflames by
percussion, but without explosion, is composed of 21 parts of nitre,
54 parts of chlorate of potassa, 18 parts of sulphur, and 7 parts of
lycopodium.
A mixture of nitre and crude antimony projected into a red-hot
crucible, produces a deflagration more or less rapid, forming a
composition which is used in pharmacy, and medicine.
The quality of saltpetre may be determined by a variety of
experiments. Fire-workers judge of its quality by the colour of its
flame.
The flame should be white. If it be _green_ or _yellow_, it is said
to be impure.
Public-domain text, read in full here on John Shaqi.
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