A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
Assuming these figures to be correct, the following statement is
approximately true. On oxidising an alloy of 10 grams of copper and 10
grams of lead, and pouring off the slag when 3 grams of lead have gone
into it, there will be a loss of (owing to the slag carrying it off)
about 0.2 gram of copper. On repeating the operation, the next 3 grams
of lead will carry with them about 0.5 gram of copper; and on again
repeating, 3 grams of lead will remove 0.8 gram of copper. Finally, the
last gram of lead will carry with it 0.3 gram of copper, and there will
be left a button of copper weighing 8.3 grams. The slag will have
carried off altogether 1.7 gram of copper, which is 17 per cent. of the
metal originally present.
With the more perfect exposure to the air, and quicker removal of the
slag, which results from heating on a cupel, the loss would be heavier.
Karsten got by actual experiment on cupelling copper and lead in equal
proportions, a loss of 21.25 per cent.
Going back to the example: if the slag were collected and fused with a
suitable reducing agent so as to convert, say, half of it into metal,
that half would contain nearly the whole of the copper (such a reduction
is called "cleaning the slag"). On reoxidising this metal, another
button of copper is formed which, added to the first, would reduce the
loss from 17 per cent. to, say, 7 or 8 per cent. And it is conceivable
that by a series of similar operations, almost the whole of the 10 grams
of copper originally taken might be recovered. In practice the problem
is (as far as the copper is concerned) not how to save, but how most
easily to remove it; and since the removal of this metal is quicker from
an alloy containing not too much lead, it is evident that two or three
operations with small quantities of lead will be more effectual than a
single treatment with a larger quantity. With those metals (tin,
antimony, &c.) which pass quickly into the slag, the contrary is true;
hence with these it is necessary to have enough lead present, so that
the slag formed at the outset shall contain enough oxide of lead to make
it fluid. As silver is so much less easily oxidised than copper, we
should reasonably expect that the proportion of silver carried off in
the oxide of lead would be considerably less than that of the copper
indicated in the above example. Indeed, there are one or two facts
which tend to encourage the hope that the operation may be conducted
without any loss. If a piece of pure silver foil is exposed on a cupel
to air at the usual temperature of cupellation, it undergoes very little
change; it does not even fuse; it loses nothing in weight, and does not
oxidise. In fact, even if oxide of silver were formed under these
conditions, it could not continue to exist, for it is decomposed into
silver and oxygen at a temperature considerably below redness. On the
other hand, oxide of silver is not reduced to metal by heat alone, when
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