A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
But the danger of spirting decreases as the proportion of
gold becomes greater, and disappears when the gold is much over 30 per
cent. Nevertheless it is well to let such buttons become solid
undisturbed and protected from draughts in the body of the muffle. This
means closing the muffle and allowing the furnace to cool down somewhat
before withdrawing the cupels. Buttons solidified in this way are more
malleable than when they are withdrawn promptly on the finish of the
cupellation. This is important with large buttons, as in a bullion
assay. On the other hand, very small buttons, especially such as have to
be measured rather than weighed, should be withdrawn as soon as the
luminous film has disappeared. For when this is done the button can be
loosened from the cupel by merely touching it with the point of a pin,
and is then safely and easily transferred to a watch glass by touching
it with the head of a pin which has been moistened. It adheres to this,
and if the pin is not too wet comes off at once on touching the glass,
or in any case will do so on gentle warming.
Molten gold, with little or no silver, has a peculiar colour which is
easy to recognise; it is more globular than a button of silver of the
same size would be, and it shows less adhesion to the cupel. Just after
becoming solid it glows beautifully, and this is so marked that it is a
valuable help in finding the position of a button when it is more than
ordinarily minute.
If the button left from cupellation is yellow it is at least half gold,
and a rough guess as to the proportion of gold may be made from its
yellowness; the rest of the metal is generally silver. The presence of
platinum or one of the platinum group of metals makes the surface of the
button dull and crystalline. The native alloy of osmium and iridium does
not alloy with gold, however, but falls to the bottom of the molten
metal. It shows itself in the subsequent parting as a black spot or
streak on the under surface.
The buttons are removed from the cupel with a pair of pliers and then
brushed to remove adherent litharge and bone-ash. Some assayers advise
cleaning by dipping in warm dilute hydrochloric acid followed by washing
in water and drying. The button is next weighed. When the quantity of
silver obtained is not required to be known the weighing may sometimes
be omitted. The next operation in either case is parting either with or
without a previous inquartation.
Public-domain text, read in full here on John Shaqi.
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