A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
_Parting in glazed crucibles or dishes._--This method of working has the
advantage that there is no transference of the gold until it is placed
on the pan of the balance. On the other hand, in the boiling more care
is required in adjusting the temperature. The following instructions
apply to the treatment of very small buttons, to which the method is
more particularly applicable; but very little modification is needed for
the treatment of larger buttons. The smallest sized Berlin crucibles
answer admirably. They should be cleaned by treatment with hot and
strong sulphuric acid, followed by washing in distilled water; the
comfort and ease of working mainly depends on the thoroughness of this
cleaning. The crucible, one-third full with the first parting acid, is
heated on the hot plate until the acid is almost boiling. The flattened
and annealed button is dropped into it and the heating continued with,
at most, gentle boiling for a few minutes. The crucible is then filled
with distilled water, which cools it enough for easy handling; and when
the gold has settled the liquor is poured off along a glass rod into a
clean beaker. Any greasiness of the crucible makes itself felt here and
is very objectionable. The crucible is then one-third filled with the
second parting acid and the heating resumed, care being taken not to
raise the temperature too high; this should be continued much longer
than before, say for five or ten minutes or even longer according to the
size of the button. Distilled water is again added and, when it is
drained off, the washing with distilled water is twice repeated. It will
not be possible to drain off the last drop of water; but if the gold is
coherent, the crucible can be so inclined that this drop drains away
from the gold, in which case the drying can be done rapidly; the boiling
of the water will do no harm. But when the gold is much broken up, it
will collect in the middle of this drop and the drying must be done
gently; best by putting the crucible in a warm place. When dry, the
crucible is heated till the gold changes colour, but the heat must be
kept well below redness. When cold, the gold is transferred directly to
the pan of the balance. With minute specks of gold which will require
measuring, it is best to put a small piece of lead foil (say .1 gram) in
the crucible over the gold, and then heat the crucible to above redness
over a blowpipe. Whilst the lead is oxidising it is easily swept round
in a bath of molten litharge by merely tilting the crucible. In this way
any separated specks of gold can be taken up with certainty. When the
worker is satisfied that the lead has had ample opportunity for taking
up the gold, the lead must be kept in one place and the heat slowly
lowered. By this means the button becomes supported in comparatively
pure litharge and when solid can be picked out quite easily with a pair
of pliers and in a very clean condition. The lead button is then
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