A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The best method of sampling such bars is to melt them all down and to
take a dip sample of the molten metal in one or other of the methods
already described. According to Mr. Claudet this should be done in all
cases where the gold exceeds one or two ounces or where the silver
exceeds 200 ozs. to the ton. If during the melting down some dross has
formed this must be skimmed off, weighed and separately sampled and
assayed. The clean lead also must be weighed, sampled and assayed. The
mean result must be calculated. Thus 14 tons 5 cwts. of clean lead
assaying 32 ozs. to the ton will contain 456 ozs. of silver; 15 cwt.
dross assaying 20 ozs. to the ton will contain 15 ozs. of silver. The 15
tons of lead and dross will contain 471 ozs. of silver or 31.4 ozs. per
ton.
Of the methods of sampling which avoid melting the bars, that known as
sawing is the only one which is thoroughly satisfactory. In it the bars
are brought to a circular saw having fine teeth and are sawn across
either completely or halfway through; in this way a quantity of lead
sawdust is obtained (say 1 lb. or so from a bar) which represents
exactly the average of the bar along the particular cross section taken
and approximately that of the whole bar. A bar of lead, which by dip
assay gave 334 ozs. to the ton, gave on three transverse sections 333
ozs., 335 ozs. and 331 ozs. The variation may be greater than this, but
with a large number of bars, where each bar is cut across in as far as
possible a different place, these variations tend to neutralise each
other and a good sample is obtained. Two or three cwt. of sawdust may be
obtained in this way; this is thoroughly mixed and reduced by
quartering in the usual way or by a mechanical sampler. A sample of 2 or
3 lbs. is sent to the assayer. This being contaminated with the oil used
in lubricating the saw is freed from it by washing with carbon
bisulphide, ether or benzene and dried. Then, after mixing, 100 to 200
grams of it are carefully weighed and placed in a hot crucible, the heat
of which should be sufficient to melt all the lead. The molten lead
should not be overheated and should show no loss due to the melting. The
removal of the oil may have decreased the weight by perhaps one half per
cent. If the lead gives dross on heating it may be melted under 10 or 20
grams of potassium cyanide, which prevents the formation of dross.
Samples are sometimes taken with a drill, gouge or chisel, though no
method of this kind is quite satisfactory. One plan adopted is to use a
punch which, when driven into the bar, gives a core or rod of metal
about half as long as the bar is thick and about one-eighth of an inch
across. With five bars side by side it is customary to drive in the
punch at one end on the first bar, and at the opposite end on the last
one, and on the others in intermediate positions in such a manner that
all the holes will be along a diagonal of the rectangle enclosing the
bars.
Public-domain text, read in full here on John Shaqi.
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