A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
other method of assay reports as full a strength in cyanide as if no
zinc were present. Unfortunately, using both methods and accepting the
difference in the results as a measure of the quantity of zinc present,
or at any rate of the zinc present as cyanide, is not satisfactory. It
appears best to use the method which ignores the zinc; and to determine
the amount of zinc by a special assay of the liquor for this metal.
The cyanide present as hydrogen cyanide or prussic acid (HCy) is
practically useless as a gold solvent. Hence any report on the strength
of a cyanide liquor which assigned to this the same value as its
equivalent of alkaline cyanide would be misleading. On the other hand,
it is "available cyanide" inasmuch as a proper addition of sodium
hydrate[38] would restore its value. The question of the presence or
absence of free prussic acid is involved in the larger one as to whether
the cyanide solution has the right degree of alkalinity. The assay for
"cyanide" should include the hydrogen cyanide with the rest.
A rough test of the power of a cyanide liquor for dissolving gold may be
made by floating a gold leaf on its surface and noting the time required
for its solution. This test might, perhaps, be improved by taking, say,
20 c.c. of the liquor and adding three or four gold leaves so that the
gold shall always be in considerable excess. The liquor should not be
diluted as this will affect the result. It should be allowed to stand
for a definite time, say at least two or three hours, or better, that
corresponding to the time the liquor is left in contact with the ore in
actual practice. The liquor should then be filtered off and, with the
washings, be evaporated in a lead dish as in the assay of cyanide
liquors for gold (p. 141). The gold obtained on cupelling, less any gold
and silver originally present in the liquor, would be the measure of the
gold dissolving power.
THE ASSAY FOR CYANIDE BY TITRATION WITH SILVER NITRATE.
The determination of the quantity of a cyanide is made by finding how
much silver nitrate is required to convert the whole of the cyanide into
potassium silver cyanide[39] or one of the allied compounds. It will be
seen from the equation that 170 parts by weight of silver nitrate are
required for 130 parts by weight of potassium cyanide. As already
explained it is customary to report the cyanide-strength in terms of
potassium cyanide, even when only the sodium salt is present. One gram
of potassium cyanide will require 1.3076 gram of silver nitrate. _The
standard solution of silver nitrate_ is made by dissolving 13.076 grams
of silver nitrate in distilled water and diluting to 1 litre; 100 c.c.
of such a solution are equivalent to 1 gram of potassium cyanide.[40]
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