A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The _standard solutions of acid and alkali_ used for this determination
may be one-fifth normal. 200 c.c. of the normal solution should be
diluted to 1 litre in each case, 1 c.c. of the resulting solutions would
be equivalent to 8 milligrams of soda (NaHO) or 5.6 milligrams of lime,
CaO. It must be remembered this refers to the pure bases in each case.
Suppose it is desired to report as so many lbs. of lime to the short ton
(2000 lbs.) of ore. Since 1 c.c. of the standard solution is equivalent
to 5.6 milligrams of lime, if we take 2000 times this weight of ore
(_i.e._ 11,200 milligrams or 11.2 grams) for the assay, each c.c. of
standard solution will be equivalent to 1 lb. of lime to the short
ton.[45]
~Total acidity.~--Weigh out 11.2 grams of the ore, place them in a
four-inch evaporating dish and measure on to it from a burette 10 or 20
c.c. of the standard solution of soda. Stir the soda solution into the
ore and allow to stand for 15 or 20 minutes with occasional stirring.
Stir up with 30 or 40 c.c. of water, float a piece of litmus paper on
the liquid and titrate with the standard solution of acid. If the ore is
strictly neutral the quantity of "acid" required to redden the litmus
will be the same as the quantity of "soda" originally used. If the ore
is acid, less acid will be used. For example, if 10 c.c. of soda were
used and only 7 c.c. of acid were required, the ore will have done the
work of the remaining 3 c.c. of acid. And the ton of ore will require 3
lbs. of lime to neutralise its acidity.
~Acidity after washing.~--Take 11.2 grams of the ore; wash thoroughly
with water and immediately treat the residue, without drying, exactly as
just described.
~Examination of cyanide solutions for metals, &c.~--Take a measured
quantity of the solution, say 20 c.c.[46] and evaporate in a small dish
with, say, half a c.c. of strong sulphuric acid. Evaporate at first, on
a water-bath in a well ventilated place, but finish off with a naked
Bunsen flame, using a high temperature at the end in order to completely
decompose the more refractory double cyanides. Allow to cool; moisten
with strong hydrochloric acid; warm with a little water and test for the
metals in the solution by the ordinary methods. Since the quantities of
the metals likely to be present may be given in milligrams the work must
be carefully performed. It may be worth while to determine the
proportions of lime and magnesia as well as those of the metals proper.
Or the 20 c.c. of cyanide liquor may be evaporated with 5 c.c. of strong
nitric acid to dryness and gently ignited and the residue taken up with
2 or 3 c.c. of strong hydrochloric acid.
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