A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
Wet methods are gradually replacing the dry assay, and it is probable
that in the future they will supersede it; for stock-taking, and the
various determinations required in smelting works and on mines, they are
generally adopted, because they give the actual copper contents, and
since it is obvious that a knowledge of this is more valuable to the
miner and smelter. Moreover, the working of the dry method has been
monopolised by a small ring of assayers, with the double result of
exciting outside jealousy and, worse still, of retarding the development
and improvement of the process.
The principal stages of the dry assay are: (1) the concentration of the
copper in a regulus; (2) the separation of the sulphur by calcining; (3)
the reduction of the copper by fusion; and (4) the refining of the metal
obtained.
The whole of these operations are not necessary with all copper
material. Ores are worked through all the stages; with mattes, the
preliminary fusion for regulus is omitted; precipitates are simply fused
for coarse copper, and refined; and blister or bar coppers are refined,
or, if very pure, subjected merely to washing.
The quantity of ore generally taken is 400 grains, and is known as "a
full trial"; but for rich material, containing more than 50 per cent. of
copper, "a half trial," or 200 grains, is used.
~Fusion for Regulus.~--The ore (either with or without a previous
imperfect roasting to get rid of any excess of sulphur) is mixed with
borax, glass, lime, and fluor spar; and, in some cases, with nitre, or
iron pyrites, according to the quality of the ore. The mixture is placed
in a large Cornish crucible, and heated as uniformly as possible in the
wind furnace, gradually raising the temperature so as to melt down the
charge in from 15 to 20 minutes. The crucible is removed and its
contents poured into an iron mould. When the slag is solid, it is taken
up with tweezers and quenched in water. The regulus is easily detached
from the slag. It should be convex above and easily broken, have a
reddish brown colour, and contain from 40 to 60 per cent. of copper. A
regulus with more than this is "too fine," and with less "too coarse." A
regulus which is too fine is round, compact, hard, and of a dark bluish
grey on the freshly broken surface. A coarse regulus is flat and coarse
grained, and more nearly resembles sulphide of iron in fracture and
colour.
If an assay yields a regulus "too coarse," a fresh determination is made
with more nitre added, or the roasting is carried further. With low
class ores a somewhat coarse regulus is an advantage. If, on the other
hand, the regulus is too fine, less nitre or less roasting is the
remedy. With grey copper ores and the oxidised ores, iron pyrites is
added.
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