A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The price of 100 tons of pyrites, containing 2-1/4 per cent. of copper
by dry assay, would be got on this standard as follows:--The parcel of
ore would contain 2-1/4 tons of copper. This multiplied by the standard
gives £160 16s. 0d. From this must be deducted the returning charge,
which for 1 ton of ore of this produce would be (12s. 2d.) + (2-1/4×(3s.
9d.)) or £1 0s. 7d., and on the 100 tons is £102 18s. 4d. This would
leave £57 17s. 10d. as the price of the parcel, or 11s. 7d. per ton.
This would be on the standard returning charge of 45s. (for 8-3/4 per
cent. ore); if a smaller returning charge was agreed on, say 38s., the
difference in this case, 7s., would be added to the price per ton.
WET METHODS.
The solubility of the ores of copper in acid has already been described,
but certain furnace products, such as slags, are best opened up by
fusion with fusion mixture and a little nitre.
The method of dissolving varies with the nature of the ore. With 5 grams
of pyrites, a single evaporation with 20 c.c. of nitric acid will give a
residue completely soluble in 30 c.c. of hydrochloric acid. If the ore
carries oxide of iron or similar bodies, these are first dissolved up by
boiling with 20 c.c. of hydrochloric acid, and the residue attacked by
an addition of 5 c.c. of nitric. When silicates decomposable by acid are
present, the solution is evaporated to dryness to render the silica
insoluble; the residue extracted with 30 c.c. of hydrochloric acid, and
diluted with water to 150 c.c. It is advisable to have the copper in
solution as chloride. To separate the copper, heat the solution nearly
to boiling (best in a pint flask), and pass a rapid current of
sulphuretted hydrogen for four or five minutes until the precipitate
settles readily and the liquid smells of the gas. When iron is present
it will be reduced to the ferrous state before the copper sulphide
begins to separate. The copper appears as a brown coloration or black
precipitate according to the quantity present. Filter through a coarse
filter, wash with hot water containing sulphuretted hydrogen, if
necessary. Wash the precipitate back into the flask, boil with 10 c.c.
of nitric acid, add soda till alkaline, and pass sulphuretted hydrogen
again. Warm and filter, wash and redissolve in nitric acid, neutralise
with ammonia, add ammonic carbonate, boil and filter. The copper freed
from impurities will be in the solution. Acidulate and reprecipitate
with sulphuretted hydrogen. When the nature of the impurities will allow
it, this process may be shortened to first filtering off the gangue,
then precipitating with sulphuretted hydrogen and washing the
precipitate on the filter first with water and then with ammonium
sulphide.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account