A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The battery used is made up of two Daniell cells, coupled up for
intensity as shown in fig. 49--that is, with the copper of one connected
with the zinc of the other. For eight or ten assays daily the quart size
should be used, but for four or five two pint cells will be sufficient.
[Illustration: FIG. 49.]
The outer pot of each cell is made of sheet copper, and must be clean
and free from solder on the inside. It is provided near the top with a
perforated copper shelf in the shape of a ring, into which the inner or
porous cell loosely fits. It is charged with a saturated solution of
copper sulphate, and crystals of this salt must be added, and always
kept in excess. When the battery is at work copper is being deposited on
the inner surface of this pot.
The inner or porous pot contains the zinc rod, and is charged with a
dilute acid, made by diluting one volume of sulphuric acid up to ten
with water. The object of the porous pot is to prevent the mixing of the
acid and copper sulphate solutions, without interrupting the flow of
electricity. The copper sulphate solution will last for months, but the
acid must be emptied out and recharged daily.
The zinc rods must be well amalgamated by rubbing with mercury under
dilute acid until they show a uniformly bright surface. They should not
produce a brisk effervescence when placed in the acid in the porous pot
before coupling up.
The battery when working is apt to become dirty from the "creeping" of
the copper and zinc sulphate solution. It must be kept away from the
working bench, and is best kept in a box on the floor.
[Illustration: FIG. 50.]
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