A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
The metal is brittle, breaks with a highly crystalline fracture, and has
a characteristic reddish-yellow colour. It is almost insoluble in
hydrochloric, but readily dissolves in nitric, acid; and gives, if the
acid is in excess, a clear solution. Bismuth salts have a strong
tendency to separate out as insoluble basic compounds; this is more
especially true of the chloride which, on diluting with a large volume
of water, becomes milky; the whole of the bismuth separating out. The
nitrate, carbonate, and hydrate yield the oxide (Bi_{2}O_{3}) on
ignition. This oxide closely resembles litharge. It combines with
silica, forming fluid slags; and at a red heat is liquid enough to be
absorbed by a cupel; in fact, bismuth may take the place of lead in
cupellation. The metal itself is easily fusible, and may be separated
from its ores by liquation.
The assay of bismuth by wet methods presents little difficulty, and is
fairly accurate. The price of the metal is such that only methods which
yield good results should be adopted; and, since bismuth is volatile at
the temperature of the furnace, and is found mixed with ores not easy to
flux, as also with metals which are not easily separated by the dry
method, the dry assay can only be considered as having a qualitative
value.
DRY ASSAY.
~By Liquation.~--This is adapted to ores containing the bismuth as
metal. Take 20 grams of the powdered ore and place in a crucible with a
perforated bottom, put this crucible into another of about the same size
and lute the joint. Lute on a cover, place in the furnace and heat to
redness. The bismuth melts readily and drains into the lower crucible
from which, when cold, it is taken and weighed.
~By Fusion.~--For fairly pure ores the process is as follows:--Take 20
grams of the ore and mix with 20 grams of fusion mixture, 10 grams of
salt and 5 or 10 grams of potassium cyanide; place in a crucible, cover,
and fuse at a moderate temperature for about fifteen minutes; pour; when
cold detach the metal and weigh.
For coppery ores in which the metals are present as sulphides use the
fluxes just given with 2 grams of charcoal (instead of the cyanide) and
a little sulphur.
For coppery ores in which the metals are present as oxides, mix 20 grams
of the ore with 10 grams of fusion mixture, 4 grams of salt, 4 grams of
sulphur and 2 grams of charcoal; and fuse.
A considerable percentage of bismuth is lost in these assays; it is
stated as being nearly 8 per cent. of the metal present.
WET METHODS.
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