A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
~Effect of Foreign Salts.~--Sodic hyposulphite almost completely removes
the colour. Copper salts liberate iodine; but when this has been removed
by boiling and the cuprous iodide has been filtered off there is no
further interference. Dilute solutions of lead salts give no colour.
PRACTICAL EXERCISES.
1. A fusible alloy is made up of 8 parts of bismuth, 5 of lead, and 3 of
tin. What weight of oxide of bismuth, Bi_{2}O_{3}, would you get on the
analysis of 1 gram of it?
2. What weight of bismuth can be got from 2 grams of the subnitrate
BiONO_{3}.H_{2}O?
3. How would you detect and separate arsenic, lead, and copper in a
sample of bismuth?
ANTIMONY.
Antimony occurs in the native state, but is rare; its common ore is
antimonite, the sulphide (Sb_{2}S_{3}). Jamesonite and other sulphides
of lead and antimony are frequently met with. Sulphide of antimony is
also a constituent of fahlerz and of many silver ores.
Antimonite occurs generally in fibrous masses, has a lead-like metallic
lustre, is easily cut with a knife, and melts in the flame of a candle.
Antimony itself has a very crystalline fracture, is brittle, and has a
bluish-white colour. It is used in the preparation of alloys with lead
and tin for the manufacture of type-metal. It is readily fusible, and
imparts hardness and the property of taking a sharp cast to its alloys.
It is practically insoluble in hydrochloric acid. On boiling with strong
nitric acid it is converted into antimonic oxide (Sb_{2}O_{5}), which is
a powder almost insoluble in this acid or in water, but which may be got
into solution with difficulty by the prolonged action of hydrochloric
and tartaric acids. Antimonic oxide is converted on ignition into the
tetroxide (Sb_{2}O_{4}) with loss of oxygen. Antimony forms two series
of salts, antimonious and antimonic; and advantage is taken of this in
its determination volumetrically. Either sulphide of antimony yields
antimonious chloride on boiling with hydrochloric acid, sulphuretted
hydrogen being given off; and, in the case of antimonic sulphide,
sulphur is deposited. Antimonious is converted into antimonic chloride
by treatment with permanganate of potash in an acid solution. Antimonic
chloride and potassium iodide react, forming antimonious chloride and
free iodine. This latter may be got rid of by boiling. Sulphide of
antimony is separated from the ore by liquation; this regulus is met
with in commerce as "crude antimony."
DRY ASSAY.
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