A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
After 1-1/4 to 1-1/2 hours (the time depending mainly on the
temperature), the contents of the crucible are usually in a state of
tranquil fusion. The pot is now lifted from the fire, and its contents
transferred to a conical iron mould, the empty pot being immediately put
back into the fire, and the latter "mended" with sufficient coke for
another run. The conical mould (when dealing with a "strange" ore, and
the possibility of insufficient iron being present to satisfy the
sulphur contents) is wiped inside with clay previous to pouring in the
molten charge. Otherwise the mould itself will be attacked, and the
contents after solidifying will require to be chiselled out piecemeal.
A further 40 lbs. of the ore is now charged into the crucible with iron
as above; but before this second charge is ready to be drawn an
inspection of the first may suggest the addition of either 3 or 5 lbs.
more iron, or 5 or 10 lbs. more ore.
It is a good fault rather to aim at an excess of iron as tending to
clean the ore from antimony, any of the latter that (from an
insufficiency of iron) may be left in the slag from the first process
being irretrievably lost; whereas, if the iron be in excess, that which
is combined with the crude antimony resulting from the first process is
easily got rid of by adding 3 to 5 lbs. or so of ore in the second
process.
This latter, as practised for the determination of the value of a parcel
of ore, consists in selecting two of the best quality singles, resulting
from perhaps four or five trials as above, and running them down with a
few pounds of salt cake, or a mixture of salt cake with American potash,
and (as is generally necessary) a small addition of ore.
Upon the final result (confirmed perhaps on another pair of singles,
and, judging from the total weight or output of the metal as calculated
from the ore used in "singling," plus any added in the "doubling," the
crystalline fracture and face of the metal, its colour, etc.) the price
to be offered for the parcel of ore is fixed.
WET METHODS.
~Detection.~--The antimony, if any, being got into solution by treating
the ore with hydrochloric acid or aqua regia may be detected by
evaporating with hydrochloric acid, diluting, and filtering into the
cover of a platinum crucible or (better) a platinum dish. A small lump
of zinc is then added, and, if antimony is present, _the dish_ will in a
minute or so be stained black with a deposit of metallic antimony. This
stain is removed by nitric, but not by hydrochloric, acid. The reaction
is delicate and characteristic; arsenic under like conditions is evolved
as arseniuretted hydrogen, and tin is deposited as metal _on the zinc_.
Public-domain text, read in full here on John Shaqi.
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