A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
(2) _With Sulphuretted Hydrogen._--Two experiments with this gas, using
in each 20 c.c. of the ferric chloride solution, and 10 c.c. of
hydrochloric acid, required (after reduction) 20.2 c.c. and 20.1 c.c. of
"permanganate." Repeating the experiments by passing the gas through a
nearly boiling solution, but in other respects working in the same way,
21.3 c.c. and 21.6 c.c. of the permanganate solution were required. The
sulphur was not filtered off in any of these. In another experiment, in
which 50 c.c. of the ferrous sulphate solution were titrated with
"permanganate," 48 c.c. of the latter were required. The titrated
solution was next reduced with sulphuretted hydrogen, brought to the
same bulk as before, and again titrated; 47.9 c.c. of the permanganate
of potassium solution were required.
(3) _With Sodium Sulphite._--Twenty c.c. of the ferric chloride
solution, reduced with sodium sulphite, required 19.9 c.c. of
"permanganate." In one experiment 50 c.c. of the ferrous sulphate
solution were titrated with "permanganate"; 49.3 c.c. of the
last-mentioned solution were required. The titrated solution was reduced
with sodium sulphite, and again titrated; it required 49.2 c.c. of the
permanganate of potassium solution.
(4) _With Zinc._--Twenty c.c. of the ferric chloride solution, reduced
with zinc and titrated, required 20.8 c.c. of "permanganate." Fifty c.c.
of a solution of ferrous sulphate which required 49.7 c.c. of
"permanganate," required for re-titration, after reduction with zinc,
49.7 c.c.
The student should next practise the titration with bichromate, which is
more especially valuable in the estimation of hydrochloric acid
solutions. The following experiments are on the same plan as those
already given. In each experiment (except when otherwise stated) there
were present 20 c.c. of the ferrous chloride solution, and 10 c.c. of
dilute hydrochloric acid, and the bulk was 300 c.c.
~Effect of Varying Temperature.~--The quantities of the bichromate of
potassium solution required were as follows:--
Temperature 15° 30° 70° 100°
Bichromate required 20.2 c.c. 20.3 c.c. 20.3 c.c. 20.4 c.c.
~Effect of Varying Bulk.~--
Bulk 50 c.c. 100 c.c. 200 c.c. 500 c.c. 1000 c.c.
Bichromate required 20.4 " 20.4 " 20.4 " 20.5 " 20.8 "
~Effect of Varying Acid.~--In these, variable quantities of dilute
hydrochloric acid were used.
Acid present 10 c.c. 50 c.c. 100 c.c.
Bichromate required 20.3 " 20.3 " 20.2 "
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account