A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
5. Two grams of a metal were dissolved and diluted to 100 c.c. Five c.c.
were taken for a colorimetric determination, and required 4.5 c.c. of
the standard ferric chloride solution. What is the percentage of iron in
the metal?
NICKEL.
Nickel and cobalt are closely related in their chemical properties, and
may best be considered together. Nickel is the commoner of the two, and
is met with in commerce alloyed with copper and zinc as German silver;
as also in the coinage of the United States and on the Continent. It is
used for plating polished iron and steel goods, forming a coating little
liable to rust and taking a good polish. The ores of nickel are not very
common. Kupfernickel and chloanthite are arsenides of nickel with,
generally, more or less iron and cobalt. Noumeite and garnierite are
hydrated silicates of nickel and magnesia. The chief sources of nickel
are these silicates, which are found in large quantity in New Caledonia;
and a pyrites found in Norway, containing three or four per cent. of the
metal. In smaller quantities it is more widely distributed, being
frequently met with in copper ores; consequently, commercial copper is
rarely free from it.
Nickel is readily soluble in moderately concentrated nitric acid. Its
salts are mostly green, and soluble in excess of ammonia, forming blue
solutions; in these respects it resembles copper. The acid solutions,
however, are not precipitated by sulphuretted hydrogen, although in
alkaline solutions a black sulphide is formed which is insoluble in
dilute hydrochloric acid. If the sulphide is formed in a solution
containing much free ammonia, the precipitation is incomplete, some
sulphide remaining in the solution and colouring it dark brown. These
reactions serve to distinguish and separate nickel from other metals,
except cobalt. If the separated sulphide be heated in a borax bead, the
colour obtained will be a sherry brown in the outer flame, and grey or
colourless in the inner flame if nickel only is present. In the presence
of cobalt these colours are masked by the intense and characteristic
blue yielded in both flames by that metal.
DRY ASSAY.
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