A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
Sulphuretted hydrogen is a strong reducing agent. Ferric salts are
thereby quickly reduced to ferrous; in hot solutions nitric acid is
decomposed. These changes are marked by a precipitation of sulphur, and
the student must be careful to pass the gas sufficiently long, and not
be too hasty in concluding that no sulphide will form because it does
not at once make its appearance. The best indication that it has been
passed long enough is the smell of the gas in the solution after
shaking.
~Sulphurous Acid~, H_{2}SO_{3}.--The reagent used may be regarded as a
saturated solution of sulphur dioxide in water. It may be purchased, and
keeps for a long time. It may be made by heating copper with sulphuric
acid and passing the gas formed into water. The heat should be withdrawn
when the gas is coming off freely. It is used as a reducing agent, and
should not be diluted.
~Sulphuric Acid~, H_{2}SO_{4}. (Sp. gr. 1.84, containing 96 per cent. of
real acid, H_{2}SO_{4}.)--This acid forms insoluble sulphates with salts
of lead, strontium, and barium. It has a high boiling point, 290° C.,
and, when evaporated with salts of the more volatile acids, converts
them into sulphates. When nitrates or chlorides are objectionable in a
solution, evaporation with sulphuric acid removes them. In working with
this acid caution is necessary, since, on mixing with water, great heat
is evolved; and, if either the acid or water has been previously heated,
a serious accident may result. In diluting the acid it should be poured
into cold water. Glass vessels containing boiling sulphuric acid should
be handled as little as possible, and should not be cooled under the
tap. The action of diluted sulphuric acid on metals closely resembles
that of dilute hydrochloric acid. Magnesium, aluminium, iron, zinc,
nickel, cobalt, manganese, and cadmium dissolve, with evolution of
hydrogen, in the cold acid, or when warmed. The action of hot and strong
sulphuric acid is altogether different; it acts as an oxidising agent,
and is itself reduced to sulphur dioxide or even to sulphur. The
following metals are attacked in this way:--copper, bismuth, mercury,
silver, antimony, tin, and lead. Gold, platinum, and arsenic are not
affected. This property is made use of in parting silver from gold and
platinum. Metallic sulphides are similarly attacked; but this method of
opening up minerals has the disadvantage of giving rise to the formation
of anhydrous sulphates of iron, &c., which are not readily dissolved
when afterwards diluted. The use of sulphuric acid in assaying is (for
these reasons) to be avoided. Its chief use is as a drying agent, since
it has a strong affinity for water. Air under a bell jar may be kept dry
by means of a basin of sulphuric acid, and gases bubbled through it are
freed from water-vapour.
~Dilute Sulphuric Acid.~--This is made by diluting 1 volume of the
strong acid with 4 of water.
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