A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
~Tartaric Acid~, H_{2}[=T] or C_{4}H_{6}O_{6}.--A crystallised organic
acid, soluble in less than its own weight of water, or in less than
three parts of alcohol. It is used for the same purposes as citric acid
is. The solution is made when required.
BASES, SALTS, &c.
~Alcohol~, C_{2}H_{6}O. (Commercial alcohol of sp. gr. 0.838; it
contains 84 per cent. by weight of alcohol.)--It should burn with a
non-luminous flame and leave no residue. It is used for washing
precipitates where water is inapplicable, and for facilitating drying.
~Ammonia~, NH_{3}. (Commercial ammonia, a solution having a sp. gr. of
0.88 to 0.89, and containing about 33 per cent. of ammonia.)--It is used
as an alkali (more commonly than soda or potash), since an excess of it
is easily removed by boiling. The salts of ammonium formed by it may be
removed by igniting, or by evaporating in a porcelain dish with an
excess of nitric acid. It differs in a marked way from soda or potash in
its solvent action on the oxides or hydrates of the metals. Salts of the
following metals are soluble in an ammoniacal solution in the presence
of ammonic chloride:--copper, cadmium, silver, nickel, cobalt,
manganese, zinc, magnesium, sodium, potassium, and the alkaline earths.
~Dilute Ammonia~ is made by diluting 1 vol. of commercial ammonia with 2
of water. The dilute ammonia is always used; but in assays for copper a
stronger solution (1 of strong ammonia to 1 of water) is required.
~Ammonic Carbonate~ (Am_{2}CO_{3}) is prepared by dissolving one part of
the commercial sesquicarbonate of ammonia in four parts of water, and
adding one part of strong ammonia.
~Ammonic Bicarbonate~ (HAmCO_{3}) is prepared by saturating a solution
of the sesquicarbonate of ammonia with carbon dioxide.
~Ammonic Chloride~, AmCl.--Use the commercial salt in a 20 per cent.
solution in water. The salt should leave no residue on ignition.
~Ammonic Molybdate.~--The solution is prepared as follows:--Dissolve 100
grams of the powdered commercial salt in 200 c.c. of dilute ammonia, and
pour the solution in a slow stream into 750 c.c. of dilute nitric acid;
make up to 1 litre, and allow the mixture to settle before using. It is
used for the purpose of separating phosphoric oxide from bases and from
other acids, and also as a test for phosphates and arsenates. In using
this solution the substance must be dissolved in nitric acid, and a
considerable excess of the reagent added (50 c.c. is sufficient to
precipitate 0.1 gram P_{2}O_{5}); when the phosphate is in excess no
precipitate will be got. The precipitate is phospho-molybdate of
ammonia.
~Ammonic Nitrate~ (AmNO_{3}) is used in the separation of phosphoric
oxide by the molybdate method, and occasionally for destroying organic
matter. It is soluble in less than its own weight of water. The solution
is made when wanted.
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