A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
With average ores, take 20 grams of the powdered ore and mix with 30
grams of "soda," 40 grams of red-lead or litharge, 5 grams of borax, and
from 2 to 2.5 grams of flour, and place in an E crucible (Battersea
round). Put these in the furnace at a red heat, cover the crucible, and
gradually raise the temperature until the whole charge has melted down
and is in a state of tranquil fusion. Pour into a mould, and replace the
crucible in the furnace. As soon as the lead is solid, detach the slag
and put it back into the crucible; and when it is again fluid, charge on
to it with a copper scoop a mixture of 20 grams of oxide of lead, and 1
gram of charcoal: when fusion has again become tranquil, pour and detach
the button of lead. The lead buttons should be hammered into discs with
rounded edges, and be freed from slag; if too big for a cupel they may
be scorified together in a small scorifier, but it is better to cupel
them separately.
~Ores containing Metallic Oxides.~--Peroxides of iron, manganese, and
copper interfere by counteracting the effect of the charcoal or flour,
and thus reducing the size of the lead button. Peroxide of iron will
reduce the weight of lead by a little more than its own weight; and
peroxide of manganese has about twice this effect. When these oxides are
present an additional quantity of flour must be used, and precautions
must be taken to prevent reoxidation of the slag by the furnace gases.
This may best be prevented by using a layer of common salt as a cover to
the charge. When the ores contain a good deal of quartz or stony matter,
the fluxes just given (for average ores) will do; but the proportion of
soda should be diminished, and that of the borax, oxide of lead, and
flour increased as the quantity of metallic oxides become greater. If
the ore contains practically no quartz, the soda may be altogether
omitted, and some glass or powdered quartz added. The following charge
may be taken as an example: weigh up 20 grams of the powdered ore, 15
grams each of "soda" and borax, 60 grams of oxide of lead, and 5 grams
of flour. Mix and place them in an E crucible, and cover with a layer of
from a quarter to half an inch of common salt. Place in the furnace as
before. The salt will give off a considerable amount of fume, which
will, to a certain extent, conceal the state of the charge: when the
crucible has been in the furnace for about 25 minutes remove it and pour
out the contents immediately. With ores that produce a thick slag the
addition of 5 grams of fluor spar will be an advantage. It may happen
that with an unknown ore the first assay will be more or less
unsatisfactory: but from it the necessity for adding more or less flour
will be learnt, and a second assay, with the necessary modification of
the charge, should give a good result.
Public-domain text, read in full here on John Shaqi.
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