A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
Silver remains after cupellation in flattened elliptical buttons,
adhering but only slightly to the cupel. Its upper surface should show
faint markings as if it were crystalline. The presence of platinum
renders it still more crystalline, but removes the characteristic lustre
and renders the metal dull and grey. Copper, if not completely removed,
has a very marked effect on the appearance of the button: the metal is
spread out, damping, as it were, and firmly adhering to the cupel, which
latter in the neighbourhood of the metal is almost black with oxide of
copper. Sometimes the silver button is globular, or even more sharply
rounded on its under than on its upper surface; it is said that this is
due to the presence of lead. Gold may be present even to the extent of
50 per cent. without showing any yellow colour.
The appearance of the cupel affords some useful information. The
presence of cracks evidently due to shrinkage indicates a badly made
cupel. If, however, they are accompanied by a peculiar unfolding of the
cupel, the margin losing its distinctness, it is because of the presence
of antimony. When lead is the only easily oxidisable metal present, the
stained portion of cupel is yellow when cold. A greenish tint may be due
to small quantities of copper or, perhaps, nickel, cobalt, or platinum.
Larger quantities of copper give a greenish grey or almost black colour.
A dark green and corroded cupel may be due to iron. Rings of
pale-coloured scoria may be due to tin, zinc, antimony, or arsenic. When
the cupel shows signs of the presence of these metals in objectionable
quantity, it is well to repeat the assay and scorify so as to remove
them before cupellation.
The button should be detached from the cold cupel by seizing with a
pair of pliers: the under surface should be distorted by squeezing or
hammering the button so as to loosen the adhering bone ash. The cleaning
is easily completed by rubbing with a clean hard brush. After cleaning
the buttons are best put on a tray of marked watch-glasses, and then
taken to the balance and weighed. The weight of silver got needs a small
correction; (1) by deducting for the amount of silver introduced by the
lead or oxide of lead used in the assay;[12] and (2) by adding for the
cupellation loss.
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