A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
In Fig. 81 is shown the Stanhope purifier, which is largely used for
the purpose of softening water. The following details will render its
action clear: A is a store tank containing caustic soda solution.
B is a tank into which the water to be treated flows, and which is
maintained at a constant level by means of a valve and float. C and C
are two tanks which are used alternately, and in which lime water is
prepared. A definite quantity of caustic soda solution is added from
B; this mixture forms the reagent by which the softening of the water
is accomplished. D is a small tank for the purpose of maintaining a
constant head of reagent. The reagent and the water are mixed together
in the pipe F, the quantities being regulated by the cocks {216}
shown at H. The pipe F leads into the vessel E, which is fitted with
a number of V-shaped shelves, placed at an angle of 45°, and riveted
alternately to opposite sides of the vessel. This arrangement causes
the water to take a serpentine course. The position of the shelves is
indicated by the dotted lines.
As soon as the mixture of water and reagent flows down the pipe F, and
enters the vessel E, the calcium carbonate commences to precipitate
and settles upon the V-shaped shelves. At the top of the tank a layer
of wood shavings, inclosed in wire-netting, is placed as shown by the
dotted lines. This acts as a filter, and intercepts any particles that
may not have subsided. The clear purified water passes away by the pipe
I.
The precipitate that collects on the V-shaped plates is from time
to time drawn off by the cocks shown at G; this may be done without
interfering with the working of the apparatus. While there can be
no doubt that the use of soft water is advantageous in the boiling,
washing, and bleaching processes, and also of course for supplying
steam boilers, it is probably an advantage to use a hard water for
diluting the pulp before running it into the machine.
In the case of papers which are loaded with any of the forms of calcium
sulphate (pearl-hardening, crystal-hardening, &c.) the use of very soft
water is objectionable from the fact that a certain quantity of calcium
sulphate is dissolved. This would not take place to the same extent
with water which is already charged with sulphate and carbonate of
calcium.
The removal of soluble iron from a water is effected by the softening
processes described.
{217}
CHAPTER XVI.
ACTION OF CUPRAMMONIUM ON CELLULOSE. PREPARATION OF WILLESDEN PAPER.
The action of a solution of copper oxide in ammonia upon cellulose
has been already referred to (see p. 5). Celluloses, and also
lignocelluloses, when treated with such a solution, gradually
gelatinise and finally dissolve. On evaporating the solution to
dryness, a gummy amorphous mass is obtained, containing the cellulose
intermixed with copper oxide.
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