A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
By decomposing a cuprammonium solution by means of metallic zinc, a
corresponding solution of zinc-ammonium hydroxide can be obtained. This
solution is also capable of gelatinising cellulose, but not to the
same extent as the copper solution. It may, however, be advantageously
employed in certain cases in conjunction with a copper solution. Such a
solution can be conveniently prepared by substituting brass for copper
in the dissolving-towers. It is worthy of note that although, as we
have seen, zinc has the power of replacing copper in a cuprammonium
solution, iron is without any action, although it readily replaces
copper in a solution {219} of copper sulphate. This fact is of very
great industrial importance, as it enables the manufacturer to employ
vessels and machinery of iron.
The “Willesden” goods may be divided into two classes. Goods of
the first class, such as rope, cordage, netting, &c., are prepared
by simply dipping the made-up materials in a bath of cuprammonium
solution, using certain precautions as to the mode of immersion and
its duration, and the strength of the solution. On subsequently drying
the dipped fabrics, they are obtained coated and impregnated with
cupro-cellulose, which thus not only forms a kind of varnish-like
surface dressing, but further adds strength to the fibres by more or
less intimately cementing them together.
Goods of the second class constitute a much more important group to
which at present the Willesden Company more especially devotes its
attention. These fabrics are essentially of three kinds, viz. Willesden
Canvas, Willesden Scrim, and Willesden Paper. The two former of these
classes are prepared in much the same way as the goods just described,
saving that the fabric to be treated is usually unwound from one roller
and rewound upon another, after passing through the bath and over a
succession of drying cylinders.
_Willesden Paper._—This may be divided into two departments, viz.
(1) Willesden unwelded; (2) Willesden welded, the first class being
prepared from a single web of paper by passing it through the bath,
rolling and drying. Certain coarse varieties furnish a waterproof
material excellently adapted for lining packages, &c. Finer qualities
furnish envelopes and stationery, possessing the valuable property
of not being affected by water. Letters written on such paper would
remain perfectly legible, even after prolonged immersion. It may be
interesting to point out here that the cuprammonium solution offers a
very simple means of fastening envelopes in such a way as to be proof
against any attempts at tampering. The method consists in using a
concentrated solution as the fastening material; the envelope {220} is
then closed and ironed with a warm flat-iron, whereby the gelatinised
cellulose is converted into an insoluble cupro-cellulose, and the cover
is fastened so securely that the only possible mode of opening is by
tearing the paper.
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