A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
After bleaching, a certain quantity of calcium hypochlorite always
remains in the pulp. It may be removed in the potcher itself, or when
the pulp reaches the beater. In any case, the methods adopted are the
same. (See p. 127.)
In some mills it is the practice to free the bleached pulp from the
products of the decomposition of the bleach by pressing the pulp in
hydraulic presses, or by draining in vats provided with perforated
bottoms. Or the pulp may be made to pass through a pulp-saver (see Fig.
52, p. 155.)
Chlorine gas as a bleaching agent has been almost entirely superseded
by the more manageable calcium hypochlorite. Its employment is open
to the serious objection indicated before, viz. the liability to form
difficultly removable chlorine compounds. Its use as a disintegrating
agent has already been alluded to (see p. 102).
A process has lately been invented (English patent, No. 11,333, 1884),
by Prof. Lunge, which involves the use of acetic acid. The quantity
required is, however, very small, as during the process of bleaching
it becomes regenerated. The free lime in the bleaching powder solution
should first be {115} nearly neutralised with a cheaper acid, such as
hydrochloric or sulphuric, followed then by the addition of the acetic
acid. This process, we are informed, gives excellent results with
high-class material, such as the best cotton and linen rags; it is,
however, not to be recommended for such materials as straw or esparto.
For the bleaching of rags the process invented by Thompson (English
patent, No. 595, 1883) has proved very effective. The method consists
in saturating the material with a weak solution of bleaching powder,
and then exposing them to the action of carbonic acid gas. In this way
the bleaching action is made very rapid and effective.
_Electrolytic Bleaching._—Various attempts have from time to time been
made to bleach by means of electricity—that is to say, by means of the
products of the electrolysis of solutions of alkaline chlorides and
the chlorides of the alkaline earths. The only process which has been
to any extent developed is that of M. Hermite. This process is based
upon the electrolysis of a solution of magnesium chloride, this salt
having been found to give the most economical results. The solution,
at a strength of about 2·5 per cent. of the anhydrous salt (MgCl_{2}),
is electrolysed until it contains the equivalent of about 3·0 grms.
chlorine per litre. This solution is then run into the “poacher”
containing the pulp to be bleached; a continuous stream is then kept
up, the excess being removed by means of a drum-washer. This excess,
which after being in contact with the pulp in the engine is more or
less deprived of its bleaching properties, is then returned to the
electrolysing vat, where it is again brought up to the normal strength.
Public-domain text, read in full here on John Shaqi.
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