A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
The bleached half-stuff as it leaves the steeping chests usually
contains an excess of bleaching liquor, which can be removed in two
ways, viz. by washing or by decomposition with an “antichlor.” The
first method has the advantage of not only removing the bleach, but
of also eliminating the chloride of calcium, partly existing ready
formed, and also that resulting from the decomposition of the calcium
hypochlorite originally present in the bleach. On the other hand, this
method takes some time, and consumes a large amount of water, which in
some mills is a matter of considerable importance. For this purpose,
many beaters are provided with one or more drum washers (see Fig. 36).
An additional objection to this method lies in the fact that a certain
quantity of fibre passes through the meshes of the wire-cloth covering
the washers, and is thus lost.
The more usual plan is to remove the bleach by decomposing it with
an “antichlor.” The substance generally employed for this purpose is
sodium hyposulphite, or thiosulphate as it is now called, which, in
presence of calcium hypochlorite, is oxidized to sodium sulphate, the
latter being reduced to calcium chloride. Double decomposition then
takes place between these salts, with the formation of calcium sulphate
and sodium chloride. The reactions which take place may be expressed by
the following equation:—
2 (Ca(ClO)_{2}) + Na_{2}S_{2}O_{3} + H_{2}O = 2 CaSO_{4} + 2 HCl + 2 NaCl.
Calcium Sodium Water. Calcium Hydrochloric Sodium
hypochlorite. thiosulphate. sulphate. acid. chloride.
{128}
The above decomposition does not accurately represent the action of
bleach upon sodium thiosulphate. If the solutions employed are very
dilute, the decomposition may take place in another direction, viz.:—
Ca(ClO)_{2} + 4 Na_{2}S_{2}O_{3} + H_{2}O = 2 Na_{2}S_{4}O_{6} + 2 NaCl
Calcium Sodium Water. Sodium Sodium
hypochlorite. thiosulphate. tetrathionate. chloride.
+ 2 NaOH + CaO.
Caustic soda. Lime.
At the particular degree of dilution which occurs in a beater, the
bleach is decomposed almost entirely according to the first of the
equations; from which, on calculating, it will be seen that 158
parts of sodium thiosulphate are equivalent to 286 parts of calcium
hypochlorite. As commercial sodium thiosulphate contains 36·3 per cent.
of water, and bleaching powder 70 per cent. of calcium hypochlorite, on
the basis of 35 per cent. available chlorine it follows that 248 parts
of the former are required to neutralize 409 parts of the latter.
Public-domain text, read in full here on John Shaqi.
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