A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
this last equivalent (62·36 _grm._ of quercitannic acid = 63 _grm._
of crystallised oxalic acid) does not differ from that of oxalic acid
more than the ordinary limits of error of such estimation, and the
substitution is therefore of no commercial importance, while it is
surely better to employ a standard which is easily and exactly verified
than one which is certain to be modified by further research, and so
to run the risk either of having our results made useless for future
comparison, or of establishing a false or arbitrary equivalent. What
is wanted for practical purposes is not the absolute weight of tannins
in the various materials, but only a means for the relative comparison
of two samples of the same material; cross comparisons of different
tannins being simply delusive. If, however, it is necessary at any time
to give actual percentages of gallotannic acid, it is probably best
to stick to Neubauer's number for the present, as it is in general
use. Neubauer states that 63 _grm._ of oxalic acid consume as much
permanganate as 41·37 _grm._ of gallotannic acid. Tshekawa found 41·688
as the equivalent for tannin from Japanese gall nuts (Chem. News,
xlii. 274). Councler and Schroeder on the other hand give only 34·3
_grm._ Simand gives 61·1 _grm._ as the equivalent of quercitannic acid.
Commercial "pure tannin" always gives results higher than the truth, as
the gallic acid which it contains consumes more permanganate than an
equal weight of tannin, or even than the tannin which would yield it
if boiled with acid. When this is done the equivalent used should be
definitely stated, or it will certainly lead to confusion. Neubauer's
equivalent is only properly applicable to gall nuts, and possibly to
sumach and myrabolans. For oak bark Oser's number or that of oxalic
acid is most likely nearly correct; and this may also be approximately
true of oak wood and valonia, but as respects all other materials we
have no information whatever, and the oxalic equivalent is as likely to
be right as any other. (Compare note, p. 128.)
[Footnote M: From researches by von Schroeder, published since the
above was penned, it seems that the permanganate consumed by tannin is
largely influenced by the way in which the titration is conducted, see
p. 128.]
A few results are given below, not as showing the relative values of
the materials, which, of course, cannot be directly compared by any
analytical process, but for comparison with those obtained by other
methods and modes of calculation:--
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