A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
Slaked lime is soluble in water at 60° F. (15° C.), to the extent of
1 part in 778. Unlike most substances, it decreases in solubility at
higher temperatures, requiring 972 parts of water at 130° F. (54° C.),
and 1270 parts at 212° F. (100° C.). Its action upon animal tissues
increases rapidly, however, with temperature, though no doubt it is
moderated to some extent by the lessened solubility. Calculating
from Dalton's numbers, pure lime-water at 60° F. (15° C.) contains
1·285 _grm._[R] of CaO per _litre_, and should require 459 _c.c._
of decinormal acid to neutralise it. This estimate in some cases
appears to be slightly too high; e. g. a saturated lime-water from
Carboniferous limestone at 56.5° F. (13° C.) required only 433 _c.c._
of decinormal acid, which equals 1·211 _grm._ of CaO per _litre_, and
this lime-water, kept with excess of lime, gave nearly constant results
for many months together. A magnesian limestone lime-water tested at
the same time required 472 _c.c._ of decinormal acid, confirming the
old observation of tanners, that such lime is stronger than that made
either from chalk or carboniferous limestone. This increased strength
must arise from the presence of some soluble base other than lime, and
may be due to the magnesia, which, however, is very slightly soluble.
Magnesian limestone contains a very large amount of magnesia, and
hence would not go so far as a purer limestone; but as a very large
proportion of the lime ordinarily used is thrown away undissolved, this
is perhaps of little practical moment. (For the chemical examination of
limes, see p. 102).
[Footnote R: 1 _grm._ per _litre_ is very approximately equal to 1 oz.
per cub. ft.]
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