A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
For sole-leather, the method recommended by Eitner is to dissolve 4-5
lb. of sulphide per gal. of water, making the solution into a thin
paste (of soupy consistence) with lime or pipe-clay. This is spread
liberally on the hair side of the hides, one man pouring it down the
middle of the hide from a pail, while another, with a mop or cane
broom, rubs it into every part. The hide is then folded into a cushion,
and in 15-20 hours will be ready for unhairing, the hair being reduced
to a paste. In the writer's experience, the concentrated solution here
prescribed will completely destroy all hair wetted with it in 2-3
hours, and if left on longer, will produce bluish patches, and render
the grain very tender. The hides should be thrown into water before
unhairing, to enable them to plump, and to wash off the sulphide,
which is very caustic, attacking the skin and nails of the workmen.
There is no doubt that this process gives good weight, and tough and
solid leather; but there are several difficulties attending its use.
Unless the mopping is done with great care, it will fail to completely
destroy the hair, and the patches of short hair left are very difficult
to remove. The expense of the material and the loss of hair are also
important considerations. The hides are rather difficult to flesh,
unless previously plumped by a light liming, and it is necessary to
swell them with acid or sour liquor in the tanhouse, as the sulphide
has but little plumping effect.
Another method, which is much cheaper in labour and easier in
execution, is to suspend in a solution of sodium sulphide, containing
3/4 lb. a hide or upwards; the hide should unhair in 24 hours. Very
weak solutions loosen the hair, without destroying it; but it is
always weakened, as the specific action of the sulphides is on the
hair itself. After or before unhairing, the hides may receive a
light liming, to plump them, or lime may be added to the solution of
sulphide, which by forming calcium sulphide, and liberating caustic
soda, considerably increases the unhairing and plumping effect. The
pit may be several times strengthened for successive packs, but
the loosened hair must be fished out, or it will quickly spoil the
solution. When hides have been suspended in sodium sulphide solution,
the hair is very quickly loosened by a short liming. Squire, Claus,
and J. Palmer have all taken out patents for the use of tank-waste
as a depilatory. It consists of impure calcium sulphides, and when
brought into the form of soluble sulphydrate, either by boiling in
water, or by the oxidising action of the air, it will unhair hides. The
conversion is, however, very imperfect in either case, and its action
is uncertain and slow; while the iron present is apt to cause unsightly
stains. It is probable that the weights obtained may somewhat exceed
those by liming. Palmer employs sulphuric acid to plump the hide and
remove stains, and then reduces it by a bate of whiting and water. He
Public-domain text, read in full here on John Shaqi.
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