A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
When unhaired and fleshed, the hides intended for sole-leather are, in
England, almost invariably "rounded," or separated into (1) "butts,"
which are the best and thickest parts, and receive the most solid
tannage, and (2) "offal," which is thinner, and for which a cheaper and
more rapid tannage is sufficient. Fig. 30 shows the customary division.
Frequently the butt is divided down the centre, and the halves are then
called "bends." A piece called a "middle" is sometimes taken between
the butt and the shoulder.
[Illustration: Fig. 30.]
After rounding, it is necessary to get rid of the lime, as completely
as possible, before taking into the tan-house. For this purpose,
the butts are usually suspended in fresh water for 12-24 hours, and
frequently shaken up in it to remove adhering lime and dirt. If
the water is hard, it is best to add to it, before putting in the
butts, a few pailfuls of clear lime-water, to precipitate the lime
bicarbonate,[T] which would otherwise cause a deposit of chalk on the
surface of the butts; this would not only make the grain harsh, but
afterwards, by combining with the tannin of the liquors, would cause
bad colour. For the same reasons, it is important that limey hides
should be as little exposed to the air as possible, as the latter
always contains a small amount of carbonic acid, which renders the lime
insoluble.
[Footnote T: Lime softens water containing lime bicarbonate in
solution by combining with half the carbonic acid, when the whole is
precipitated as normal carbonate or chalk. CaO + CaCO_{3} . H_{2}CO_{3}
= 2CaCO_{3} + OH_{2}. This is Clark's process. See also p. 84.]
This suspension in water is frequently considered sufficient for
sole-leather, but it removes the lime very imperfectly. In olden days,
it was customary not only to wash the hides much more thoroughly in
water, but to "scud" them (i.e. work them over with a blunt knife),
to remove lime, and the detritus of hair-roots and fat-glands, and
this should never be omitted from sole-leather treatment where bright
colour and clean buff are desired. Some tanners go so far as to bate
best butts slightly with hen-dung, but with such treatment firmness
and weight are lost. Washing in weak solution of sugar, or ammonic
chloride or sulphate, or of sulphuric, or hydrochloric acid, may be
adopted. It is essential to use acids nearly free from iron, as it may
be precipitated on the butts and give a bluish colour in the liquors,
and the acid must be of such a strength as neither to allow the iron
to be precipitated, nor, on the other hand, perceptibly to plump the
butts, which in this stage would endanger buff and colour. 100 _cc._
may neutralise 15-20 _cc._ of lime-water for this purpose. Hydrochloric
acid and chlorides have a tendency to prevent plumping, and are
therefore better adapted for dressing than for sole leather. Great
care must also be taken to prevent putrefaction, or the use of putrid
solutions, if firmness and plumpness are desired.
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