A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
In this they are retained for some days, being handled frequently.
They completely lose their plumpness, and become soft and slippery;
the caustic lime is entirely removed; and the remaining portions of
hair-sheaths and fat-glands are so loosened that they are easily worked
out by a blunt knife on the beam. This final cleansing process is
called "scudding." The theory of the action of the "bate," or "pure,"
as it is sometimes called, is somewhat imperfect. It is frequently
attributed to the action of ammonia salts, and phosphates, contained
in the fermenting dung. Ammonia salts certainly will remove caustic
lime, free ammonia being liberated in its place, and weak solutions
of ammonia sulphate or chloride will rapidly reduce hides, and remove
or neutralise the lime. The phosphates in dung are mostly, if not
entirely, in the form of lime phosphate, which is quite inert. In
point of fact, the process seems to be a fermentive one, the active
bate swarming with _bacteria_; to this, rather than to its chemical
constituents, its action must be attributed. The _bacteria_ act not
only on the organic constituents of the dung, but on those of the hide,
producing sulphuretted hydrogen, together with tyrosin and leucin,
and other weak organic acids, which neutralise and remove the lime,
and, at the same time, soften the hide by dissolving out the coriin,
and probably also portions of the gelatinous fibre. The truth of this
theory is supported by the fact that, in warm weather, the activity
of the bate is greatly increased, and that, if one pack of hides is
over-bated, the next following is much more severely affected, the
hides having in fact themselves furnished food for the multiplication
of the bacterian ferment from the destruction of their own tissues.
It also explains the effective use (as a substitute) of warm water
with a very small portion of glucose, which, in itself, would be
insufficient to dissolve the lime, but with a small quantity of
nitrogenous matter, forms an excellent _nidus_ for the multiplication
of these organisms. An American invention for bating is the use of old
lime-liquor neutralised with sulphuric acid, an idea which is much more
scientific than would at first sight appear. Old lime-liquors, as we
have seen (p. 143) contain much ammonia and weak organic acids, such as
caproic, amidocaproic (leucin), and tyrosin. On adding sulphuric acid,
the lime forms an inert sulphate, and the sulphate of ammonia and the
weak organic acids which remain dissolved are just what are required
in a chemical bate. The lime-liquor should of course be filtered or
settled clear before using, and enough acid added barely to neutralise
the lime, and the liquor again settled or filtered. By this means both
the dissolved gelatin and the iron of the acid will be got rid of. The
liquor might then be slightly acidified before use. The writer has no
experience of the method, but imagines that used as described it might
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