A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
peculiar mustard-like odour, and the water at first present has been
entirely replaced by oil. The later dryings are frequently conducted
in a heated room, and when the oiling is complete, the skins are piled
on the floor, and the oxidation of the oil, which has already commenced
during the fullings and dryings above described, is completed by a sort
of fermentation, in which the skins heat very considerably. During this
process, they are carefully watched, and if the heat rises so high as
to endanger the quality of the leather, the pile must be turned over,
so as to cool the skins, and bring those which were originally outside
to the centre. When the fermentation comes to an end, the skins are
no longer susceptible of heating, and are of the well-known yellow or
chamois colour. Where this colour is objectionable, the oxidation is
sometimes completed by hanging the leather in a heated room instead
of by piling. It is now necessary to remove the surplus oil, and this
in France is done by oiling with any sort of oil, throwing into hot
water, and wringing or squeezing. The oil obtained in this way forms
the _moëllon_ or _dégras_ so much prized for currying purposes. The
unoxidised oil still retained by the skins is removed by washing
with soda or potash lye. In England and Germany, the whole of the
uncombined oil is removed in this way, and is recovered from the lye,
in which it exists in a partially saponified state, by neutralisation
with sulphuric acid. It forms the "sod" oil of commerce. About half
the oil employed is obstinately retained by the skin, and cannot be
removed even by boiling with alkalies, while no gelatin is obtained
by boiling water, to which the chamoised skin is much more resistant
than ordinary leather. The nature of the tanning process does not seem
to be well understood. It is generally stated that the fibres of the
skin are unaltered, but are merely coated with the oxidised products of
the oil. It is hard, however, on this hypothesis to understand their
extraordinary indifference to water, even at a boiling temperature,
which speedily converts kid and other tawed leathers into a solution
which gelatinises on cooling; and it seems more probable to the present
writer that some actual chemical combination is formed. Lietzman
('Herstellung der Leder,' p. 164) supposes that the whole of the
gelatigenous tissue has been removed by liming and bating, and that
only the very indifferent yellow elastic fibres (see p. 21) remain.
This view, however, is quite untenable, in consideration of the very
small proportion of these fibres originally present in the skin. Müntz,
in his researches (see p. 17), showed that the fibres insoluble in
boiling water scarcely exceeded 3 per cent, of the dried pelt. Dry
gelatigenous fibre has a considerable resistance to heat, and it is
possible that the action of the oil may consist in preventing the
absorption of water. This, however, will not explain its resistance to
alkalies.
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