A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
_Standard Solutions._--If 40 _grm._ of pure caustic soda (NaHO) be
dissolved in water, and a little tincture of litmus added, it will be
coloured a bright blue. If hydrochloric acid be now added, drop by
drop, the litmus will at last become purple, and a single drop more
would turn it a bright red. At this point the liquid is neither acid
nor alkaline, and if it be evaporated to dryness, nothing will be left
but 58·5 _grm._ of common salt (NaCl), while 18 _grm._ of water will
be formed and have escaped. We have therefore used exactly 36·5 _grm._
of pure HCl, and if we dissolve 40 _grm._ of caustic soda in 1 _litre_
of water, and 36·5 _grm._ of pure HCl in another, equal parts of these
liquids will always exactly neutralise each other, forming nothing
but common salt and water. It will be obvious that if we have a soda
solution of the strength named, we can find the amount of hydrochloric
acid in any solution of unknown strength, by seeing how much of it
is required to neutralise, say, 10 _c.c._ (= 0·4 _grm._ soda) of the
known solution. Instead of 40 _grm._ of caustic soda, we may take 56
_grm._ of potash to the _litre_, and it will exactly neutralise an
equal volume of the hydrochloric solution containing 36·5 _grm._ If,
again, we make a solution containing 49 _grm._ of pure sulphuric
acid (SO_{4}H_{2}) per _litre_, it will neutralise an exactly equal
volume of either the soda or the potash solution, thus being precisely
equivalent to the HCl solution. Such solutions are called normal, and
any normal acid solution will neutralise an equal volume of any normal
alkali, and _vice versâ_. For many purposes normal solutions are too
strong, and solutions containing 1/10 of the quantities required for
normal solution are preferable; such solutions are called decinormal.
All solutions containing known quantities of chemicals, and intended
for use in volumetric analysis, are called Standard solutions.
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