A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
_Detection of other Impurities._--Sulphuric acid (as sulphates) is
seldom wholly absent, but its presence may be proved, by adding excess
of barium chloride to the water slightly acidified with hydrochloric
acid (2-3 _c.c._ of saturated solution of BaCl_{2} are sufficient for
any ordinary water); if the mixture be allowed to stand overnight in a
100 _c.c._ cylinder beside a solution containing a known, and not very
different quantity of decinormal sulphuric acid, the quantity present
may be roughly compared by measuring the bulk of the precipitates.
Lime may be similarly detected and roughly measured by precipitation
with excess of ammonic oxalate in presence of ammonium chloride, to
hinder precipitation of magnesia. Lime-water, which may be used as a
standard, contains about 128 parts of lime per 100,000.
Magnesia is detected by adding ammonium phosphate to the filtrate from
the precipitated oxalate of lime. If the mixture be allowed to stand
in a warm place for 24 hours all the magnesia will be precipitated as
ammonio-magnesic phosphate.
Silica, &c.--100 _c.c._ of the water is acidified with a little HCl
evaporated to dryness, moistened with HCl, and treated with a little
hot water. The silica or silicic acid is left undissolved. The solution
from which the silicic acid has been filtered off is evaporated to
small bulk and ammonia added, when iron will be precipitated as brown
ferric oxide, which is coloured black by tannin or tanning liquor.
If copper be present it will give a blue solution with the ammonia.
Iron may also be recognised by evaporating the water to small bulk
with a trace of HCl, and adding a little sodium acetate, when if
iron be present it will be coloured black by tannin, red by ammonium
sulphocyanide, and blue by potassium ferrocyanide (prussiate of
potash). Its quantity may be estimated (Thomson, Chem. Soc. Abstracts,
May 1885) by measuring 100 _c.c._ of the water to be tested and 100
_c.c._ distilled water into two similar cylinders, adding to each 5
_c.c._ of dilute hydrochloric acid (1:5) and 15 _c.c._ of a solution
of potassium sulphocyanide (40 _grm._ per _litre_), and then adding to
the distilled water cylinder a very dilute standard solution of ferric
salt, till its colour matches the other. If the iron contained in the
water is in the ferrous condition, it must be oxidised with potassic
permanganate before testing.
A suitable ferric standard solution may be made by dissolving 0·1
_grm._ of clean, bright, soft iron wire in a little hydrochloric acid
in a long-necked flask, adding nitric acid so long as red fumes are
produced, evaporating nearly to dryness, and making up to 1 _litre_
(more accurately 996 _c.c._). Each _c.c._ will then equal 0·0001 _grm._
Fe.
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