A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
The filter is then dried and the precipitate is placed in a platinum
crucible and first gently, and then strongly ignited with the cover on;
the filter paper, freed as much as possible from the precipitate, is
burnt in the usual way on the crucible lid, the ashes are added to the
precipitate in the crucible, and the whole is again ignited and allowed
to cool in the desiccator, and finally weighed. 111 parts of magnesia
pyrophosphate correspond to 120 parts of acetic, or 180 parts of lactic
acid. Kohnstein and Simand calculate the pyrophosphate corresponding to
the acetic acid already found by distillation, and after deducting it
reckon out the remainder as lactic acid. Of course the volatile acids
are really a mixture consisting of acetic, propionic, butyric and other
members of the fatty group; but it would be difficult if not impossible
to separate them. Similarly other fixed acids exist in mixture beside
the lactic acid, but as their action is similar and lactic acid is
always the most abundant, these acids are to be reckoned as lactic.
It has been mentioned that when sulphuric acid is present in the liquor
it is found in the filtrate from the magnesia carbonate as sulphate.
After removal of the lime as oxalate, as previously described, the
magnesia may be similarly determined as pyrophosphate, and reckoned
out as sulphuric acid (111 parts of pyrophosphate being equal to 98
parts sulphuric acid, H_{2}SO_{4}). It may also be estimated with
barium chloride, but in this case regard must be had to the sulphates
originally present in the liquor.
Since waters invariably contain both lime and magnesia salts, a
portion (50 or 100 _c.c._) must be evaporated, ignited, and after
precipitation of the lime, the magnesia must be estimated as already
described, and deducted from the amount found in a similar amount of
liquor after saturating with magnesia. If, together with the organic
acids, the liquor contains sulphuric acid, the correction may be
divided equally between the two.
The method is not applicable in presence of phosphoric, tartaric, or
oxalic acids. To overcome this difficulty, Messrs. Kohnstein and Simand
are at present investigating a method dependent on decolorisation of
the liquor with bone charcoal, completely free from mineral salts, and
subsequent titration with soda.
It may be interesting to add the determinations of a complete set of
handlers in a Continental upper-leather tannery, in which larch bark is
used. 100 _c.c._ of liquor contained as follows, in _grm._:--
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account